In the gas phase methyl isocyanide, H,CNC, rearranges to form ethanenitrile, H,CCN. H,C-NC H,C-CN The table below shows the experimentally determined values of the rate constant for t rearrangement at different temperatures. Temperature / °C Rate constant/s 190 2.52 x 10 199 5.25 x 10 230 6.30 x 10* 251 3.16 x 103 a) Determine the overall order of the reaction. Write the rate expression for the reaction. Using a graphical method, determine the activation energy for the rearrangement of isocyanide.

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2 In the gas phase methyl isocyanide, H,CNC, rearranges to form ethanenitrile, H,CCN.
H,C-NC
H,C-CN
The table below shows the experimentally determined values of the rate constant for this
rearrangement at different temperatures.
Temperature / °c
Rate constant / s
190
2.52 x 10
199
5.25 x 10
230
6.30 х 10*
251
3.16 х 103
(a) Determine the overall order of the reaction.
(b) Write the rate expression for the reaction.
(c) Using a graphical method, determine the activation energy for the rearrangement of methyl
isocyanide.
(d) Determine the value of the rate constant for this reaction at (i) 210 °C and (ii) 283 °C.
Transcribed Image Text:2 In the gas phase methyl isocyanide, H,CNC, rearranges to form ethanenitrile, H,CCN. H,C-NC H,C-CN The table below shows the experimentally determined values of the rate constant for this rearrangement at different temperatures. Temperature / °c Rate constant / s 190 2.52 x 10 199 5.25 x 10 230 6.30 х 10* 251 3.16 х 103 (a) Determine the overall order of the reaction. (b) Write the rate expression for the reaction. (c) Using a graphical method, determine the activation energy for the rearrangement of methyl isocyanide. (d) Determine the value of the rate constant for this reaction at (i) 210 °C and (ii) 283 °C.
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