In the famous Haber process (Figure SAT12.4PI) to manufacture ammonia, the reaction is carried out at pressures of 800 to 1000 atm and at 500 to 600°C using a suitable cata- lyst. Only a small fraction of the material entering the reactor reacts on one pass, so recy- cle is needed. Also, because the nitrogen is obtained from the air, it contains almost 1% rare gases (chiefly argon) that do not react. The rare gases would continue to build up in 72 Recycle, Bypass, Purge, & the Industrial Application Material Balances Chap. 12 the recycle until their effect on the reaction equilibrium would become adverse. There- fore, a small purge stream is used. 3H2 + N2 + 2NHS N2 - Separator - NH3 (Liquid) H2 Reoctor Ar N2, H2, Ar Purge (Gas) Figure SAT12.4P1 The fresh feed of gas composed of 75.16% H2, 24.57% N2, and 0.27% Ar is mixed with the recycled gas and enters the reactor with a composition of 79.52% H2. The gas stream leaving the ammonia separator contains 80.01% H, and no ammonia. The product ammonia contains no dissolved gases. Per 100 moles of fresh feed: a. How many moles are recycled and purged? b. What is the percent conversion of hydrogen per pass?
In the famous Haber process (Figure SAT12.4PI) to manufacture ammonia, the reaction is carried out at pressures of 800 to 1000 atm and at 500 to 600°C using a suitable cata- lyst. Only a small fraction of the material entering the reactor reacts on one pass, so recy- cle is needed. Also, because the nitrogen is obtained from the air, it contains almost 1% rare gases (chiefly argon) that do not react. The rare gases would continue to build up in 72 Recycle, Bypass, Purge, & the Industrial Application Material Balances Chap. 12 the recycle until their effect on the reaction equilibrium would become adverse. There- fore, a small purge stream is used. 3H2 + N2 + 2NHS N2 - Separator - NH3 (Liquid) H2 Reoctor Ar N2, H2, Ar Purge (Gas) Figure SAT12.4P1 The fresh feed of gas composed of 75.16% H2, 24.57% N2, and 0.27% Ar is mixed with the recycled gas and enters the reactor with a composition of 79.52% H2. The gas stream leaving the ammonia separator contains 80.01% H, and no ammonia. The product ammonia contains no dissolved gases. Per 100 moles of fresh feed: a. How many moles are recycled and purged? b. What is the percent conversion of hydrogen per pass?
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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