In order to calibrate a constant volume bomb calorimeter, the combustion of (4.336x10^-1) g of benzoic acid, CóH5COOH, was observed to cause the temperature in the calorimeter to rise from 25.000 to (2.76178x10^1) °C. The energy of combustion of benzoic acid, A, is -3226.7 kJ mol-1. What is total heat capacity (C) of the calorimeter (including all its contents) in kJ °C-1?

In order to calibrate a constant volume bomb calorimeter, the combustion of (4.336x10^-1) g of benzoic acid, CóH5COOH, was observed to cause the temperature in the calorimeter to rise from 25.000 to (2.76178x10^1) °C. The energy of combustion of benzoic acid, A, is -3226.7 kJ mol-1. What is total heat capacity (C) of the calorimeter (including all its contents) in kJ °C-1?

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

See similar textbooks

Similar questions

4b. Combustion of 3.500 g of butane gas (C4H10; Mm = 58.12 g/mol) causes a temperature rise (AT) of 29.09°C in a constant-pressure calorimeter that has a heat capacity (C,) of 5.500 kJ/°C. o Use calorimetry to calculate the heat (q,) released by the combustion of 3.500 g of butane gas in the calorimeter Яр [ Select ] kJ / 3.500 g of C4H10 o Use the heat (qp) released by the combustion of 3.500 g of butane gas, calculated in part (a) to calculate the change in enthalpy (AHrxn) for the following reaction. (for 1 mole of butane gas): C4H10(9) + 13/2 02(9) → 4 CO2(9) + 5 H20(g) AHrxn [ Select ] kJ / mol of C4H10 • Use the heats of formation (AH¢°) to calculate the change in enthalpy (AHrxn) for the same reaction. (for 1 mole of butane gas): Heats of Formation: CO2 (g) - A H°f = -393.5 kJ/mol H2O(g) - A H°f = -241.8 kJ/mol O2 (9) - A H°f 0.0 kJ/mol C4H10 (g) - A H°f = -125.6 kJ/mol C4H10(g) + 13/2 02(g) → 4 CO2(9) + 5 H20(g) ΔΗη [ Select ] kJ / mol of C4H10
Part B 2.0000 g of the unknown compound is burned in a bomb calorimeter. During the combustion, the temperature of the calorimeter increases from 23.125°C to 28.997 °C. During calibration, the heat capacity of the calorimeter was found to be 9.9897kJ °C-1. In the previous experiment, the molar mass of the substance was found to be 148.16 gmol-1. What is AcombU for the unknown compound? να ΑΣφ ? kJ mol1 Submit Request Answer
In this experiment you will place a sample of your salt in water in a constant pressure calorimeter. You will determine the enthalpy change for the dissociation of your salt, Delta Hdiss. A sample of 4.368 grams of the salt SrCl2 was placed in 35.5 g water, the initial temperature was 20.00℃ and the final temperature was 27.086365℃. What is the number of moles of SrCl2? 4.368 g SrCl2 x ( 1 mol SrCl2 / 123.073 g SrCl2 ) = 0.035491131 mol SrCl2 a. 0.035491 mol SrCl2 b. none of these c. 0.035 mol SrCl2 d. 0.03 mol SrCl2 e. 0.0355 mol SrCl2 f. 0.04 mol SrCl2 g. 0.035491131 mol SrCl2 h. 0.03549 mol SrCl2
To study the possible amount of energy generated by a person, the person can be roughly viewed as a constant pressure calorimeter using table sugar (sucrose, C12H22O11) as the energy generator. The reaction of table sugar in a calorimeter is given by: C12H22O11(s) + 12O2(g) ----------> 12CO2(g) + 11H2O(g) a. What is the heat released by consuming one mole of sugar (C12H22O11) in this way? b. Calculate the enthalpy of combustion per mole of sugar utilization. c. Does the result of your calculation make sense?
Fructose, C6H12O6(s), is a sugar closely related to glucose. A 0.755 g sample of fructose was combusted with excess oxygen in a bomb calorimeter, containing 500.0 g of water. The heat capacity of the empty calorimeter was 208 J/K. The temperature of the calorimeter and the water rose from 22.00°C to 27.12°C due to the combustion reaction, which formed CO₂(g) and liquid water. What is the energy change, AU (in kJ), for the combustion of one mole of fructose under these conditions? O +254 O-15600 -2810 +520 -804
Find the molar enthalpy of combustion in kJ/mol of glucose at some temperature and pressure C6H12O6 (s) + 6 O2 (g) → 6 CO2 (g) + 6 H2O (l) given that in an experiment under the same conditions the combustion of 0.108 g of glucose raised the temperature of a calorimeter with total heat capacity C= 1.155 kJ/°C by 1.31 °C. The molar mass of glucose is 180.1 g/mol. Ignore the heat absorbed by the combustion products; assume this is negligible, and all heat went into the calorimeter itself. Give the answer with 5 or more significant figures.
Calcium acetate, Ca(CH3COO)2 has a molar mass of 158.17 g/mol. In a constant pressure calorimeter, 44.2 g of Ca(CH3COO)2 is dissolved in 861g of water at 25.00 °C. The heat produced by the solution was determined to be 15kJ. What is the final temperature of the solution? q= - msAT SH20 = 4.184 29.0 °C O 18.4 °C O 64.6 °C O 33.8 °C O 3.96 °C O 21.0 °C
At constant volume, the heat of combustion of a particular compound is -3916.0 kJ/mol. When 1.329 g of this compound (molar mass = 166.62 g/mol) was burned in a bomb calorimeter, the temperature of the calorimeter, including its contents, rose by 7.549 "C. What is the heat capacity (calorimeter constant) of the calorimeter? calorimeter constant: kJ/ "C
A bomb calorimeter, or constant volume calorimeter, is a device often used to determine the heat of combustion of fuels and the energy available from foods. Since the "bomb" itself can absorb energy, a separate experiment is needed to determine the heat capacity of the calorimeter. This is known as calibrating the calorimeter. In the laboratory a student burns a 0.508-g sample of benzil (C14H1002) in a bomb calorimeter containing 1060. g water. The temperature increases from 24.70 °C to 27.80 °C. The specific heat capacity of water is 4.184 J gl°C1. The combustion enthalpy is -6784 k]/mol benzil. C14H1002(s) + 31/2 02(g) →14 CO2(g) + 5 H20(I) A,H° = -6784 kJ/mol %3D Calculate the heat capacity of the calorimeter. heat capacity of calorimeter = J/C
CH,,0, (s) + 60, (g) → 6CO, (g) + 6H,0(g) 12 The combustion of glucose was performed in a bomb calorimeter. Qwater= 14.52kJ. The heat capacity of the bomb is Ca = 2.273 kJ/C and the change in temperature was 28.49C. If 0.03255 moles of glucose was used in the bomb calorimeter, then what is AHmy in kJ/mol? a. ´cal rnx
When 0.430 g of biphenyl (C12H10)( undergoes combustion in a bomb calorimeter, the temperature rises from 26.8 ∘C to 29.7 ∘C Find ΔErxn for the combustion of biphenyl. The heat capacity of the bomb calorimeter, determined in a separate experiment, is 5.86 kJ/∘C Express the energy in kilojoules per mole to three significant figures.
The enthalpy of combustion of benzoic acid is commonly used as the standard for calibrating constant-volume bomb calorimeters; its value has been accurately determined to be -3226.7 kJ/mol. When 1.9862 g of benzoic acid are burned in a calorimeter, the temperature rises from 21.84 degrees Celsius to 25.67 degrees Celsius. What is the heat capacity of the bomb in kJ/degrees Celsius?