In most instances hydrolysis of an alkylhalide is catalyzed by hydroxide ion. However, the rate of hydrolysis of t-butyl chloride in aqueous ethanol is almost unaffected by addition of potassium hydroxide. Suggest a reason for this and explain why this effect is observed with a t-butyl compound. Illustrate your answer.
In most instances hydrolysis of an alkylhalide is catalyzed by hydroxide ion. However, the rate of hydrolysis of t-butyl chloride in aqueous ethanol is almost unaffected by addition of potassium hydroxide. Suggest a reason for this and explain why this effect is observed with a t-butyl compound. Illustrate your answer.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:In most instances hydrolysis of an alkylhalide is catalyzed by hydroxide ion. However, the
rate of hydrolysis of t-butyl chloride in aqueous ethanol is almost unaffected by addition of
potassium hydroxide. Suggest a reason for this and explain why this effect is observed with
a t-butyl compound. Illustrate your answer.
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