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In hydration of alkenes, Is hyohoboration always give a non-Markovonikov product? Is oxymercuration always give a Markovonikov product? In syntheisis of diols, Is hydroxylation always give a Cis 1,2 diol? Is mCPBA (meta-chloroperoxybenzoic acid) always give a tran 1,2-diol?

In hydration of alkenes, Is hyohoboration always give a non-Markovonikov product? Is oxymercuration always give a Markovonikov product? In syntheisis of diols, Is hydroxylation always give a Cis 1,2 diol? Is mCPBA (meta-chloroperoxybenzoic acid) always give a tran 1,2-diol?

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Can some one help to explain this slide? 

In hydration of alkenes, Is hyohoboration always give a non-Markovonikov product?

Is oxymercuration always give a Markovonikov product?

In syntheisis of diols, Is hydroxylation always give a Cis 1,2 diol?

Is mCPBA (meta-chloroperoxybenzoic acid) always give a tran 1,2-diol?

Pleease give backgound informations, and details to support the explanation.

(Please draw the Mechanism to help me understand the principle if you can)

(14) Chapter 17: Alcohols and Phenols Chydration of alkenes hychroboration BH3 THE Hg(OAc)3 H₂O oxymercuration CH 3 Preparation (Review) synthesis of diols. hydroxylation 0s 04 руг a -OOH MCPBA CH₂Cl₂ CH3 H H BH₂ CH3 H₂O₂ -OH OH H H₂O Ac CH3 H osmate ..CH3 Na BHy "MCPBA= meta-chloro peroxybenzoic acid epoxide CH3 H OH reduction NaHSO3 H₂O non - Markovnikov product CH3 acid-catalyzed hydrolysis H30 OH Markovnikov product CH3 a OH OH OH H cis 1,2-diol CH 3 OH tran 1,2-diol
Transcribed Image Text:(14) Chapter 17: Alcohols and Phenols Chydration of alkenes hychroboration BH3 THE Hg(OAc)3 H₂O oxymercuration CH 3 Preparation (Review) synthesis of diols. hydroxylation 0s 04 руг a -OOH MCPBA CH₂Cl₂ CH3 H H BH₂ CH3 H₂O₂ -OH OH H H₂O Ac CH3 H osmate ..CH3 Na BHy "MCPBA= meta-chloro peroxybenzoic acid epoxide CH3 H OH reduction NaHSO3 H₂O non - Markovnikov product CH3 acid-catalyzed hydrolysis H30 OH Markovnikov product CH3 a OH OH OH H cis 1,2-diol CH 3 OH tran 1,2-diol
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