In aqueous solution cobalt(II) ion is surrounded by 4 water molecules and has a light pink color. When high concentrations of chloride ion are introduced, a cobalt-chloride complex ion forms that has a distinctive blue color. One way to represent this equilibrium is: CoCl (aq) Co2*(aq) + 4 Cl (aq)

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**Dynamic and Static Equilibrium in Cobalt-Chloride Ion Reactions**

In aqueous solution, cobalt(II) ion is surrounded by 4 water molecules and exhibits a light pink color. When high concentrations of chloride ion are introduced, a cobalt-chloride complex ion forms, which has a distinctive blue color.

**Representation of Equilibrium:**

\[ \text{CoCl}_4^{2-} (\text{aq}) \xrightleftharpoons{} \text{Co}^{2+} (\text{aq}) + 4 \text{Cl}^- (\text{aq}) \]

*Visual Description:*
- On the left, an image shows a test tube with a deep blue solution, representing the cobalt-chloride complex ion (\(\text{CoCl}_4^{2-}\)).
- On the right, an image depicts a test tube with a light pink solution, representing the cobalt(II) ion (\(\text{Co}^{2+}\)) surrounded by water molecules.

**Experimental Setup:**

An experiment was conducted to demonstrate dynamic equilibrium between these two ions. A special form of \(\text{CoCl}_4^{2-}\) (aq) was used, where one of the chloride ions was isotopically labeled (\(^{36}\text{Cl}\) in place of the naturally occurring isotopes). The system was allowed to reach equilibrium.

**Labeling in the Structure:**

\[
\text{Cl}
\hspace{10pt}
^{36}
\hspace{-3pt}
\text{Cl}
\hspace{10pt}
\text{Cl}
\hspace{10pt}
\text{Cl}
\hspace{10pt}
||
\hspace{10pt}
\text{Co}
\hspace{20pt}
^-2
\]

**Interpreting Dynamic vs. Non-Dynamic Equilibrium:**

If the equilibrium is **NOT dynamic**, the forward reaction would run until equilibrium is reached and then cease. Under this condition, which of the structures below would be observed for \(\text{CoCl}_4^{2-}\)?

If the equilibrium **IS dynamic**, the forward and reverse reactions run even after equilibrium is reached. Under this condition, which of the structures below would be observed for \(\text{CoCl}_4^{2-}\)?

**Provided Structures:**

A.
\[
\text{Cl}
\
Transcribed Image Text:**Dynamic and Static Equilibrium in Cobalt-Chloride Ion Reactions** In aqueous solution, cobalt(II) ion is surrounded by 4 water molecules and exhibits a light pink color. When high concentrations of chloride ion are introduced, a cobalt-chloride complex ion forms, which has a distinctive blue color. **Representation of Equilibrium:** \[ \text{CoCl}_4^{2-} (\text{aq}) \xrightleftharpoons{} \text{Co}^{2+} (\text{aq}) + 4 \text{Cl}^- (\text{aq}) \] *Visual Description:* - On the left, an image shows a test tube with a deep blue solution, representing the cobalt-chloride complex ion (\(\text{CoCl}_4^{2-}\)). - On the right, an image depicts a test tube with a light pink solution, representing the cobalt(II) ion (\(\text{Co}^{2+}\)) surrounded by water molecules. **Experimental Setup:** An experiment was conducted to demonstrate dynamic equilibrium between these two ions. A special form of \(\text{CoCl}_4^{2-}\) (aq) was used, where one of the chloride ions was isotopically labeled (\(^{36}\text{Cl}\) in place of the naturally occurring isotopes). The system was allowed to reach equilibrium. **Labeling in the Structure:** \[ \text{Cl} \hspace{10pt} ^{36} \hspace{-3pt} \text{Cl} \hspace{10pt} \text{Cl} \hspace{10pt} \text{Cl} \hspace{10pt} || \hspace{10pt} \text{Co} \hspace{20pt} ^-2 \] **Interpreting Dynamic vs. Non-Dynamic Equilibrium:** If the equilibrium is **NOT dynamic**, the forward reaction would run until equilibrium is reached and then cease. Under this condition, which of the structures below would be observed for \(\text{CoCl}_4^{2-}\)? If the equilibrium **IS dynamic**, the forward and reverse reactions run even after equilibrium is reached. Under this condition, which of the structures below would be observed for \(\text{CoCl}_4^{2-}\)? **Provided Structures:** A. \[ \text{Cl} \
**Dynamic Equilibrium Experiment**

In this experiment, we are examining the dynamic equilibrium of the reaction:

\[ \text{N}_2\text{O}_4 \, (\text{g}) \rightleftharpoons \, 2 \, \text{NO}_2 \, (\text{g}) \]

The goal is to demonstrate the concept of dynamic equilibrium. We start with a special form of \( \text{N}_2\text{O}_4 \) in which one of the oxygen atoms is isotopically labeled with \( ^{18}\text{O} \) instead of \( ^{16}\text{O} \). The system is then allowed to reach equilibrium.

![Image of chemical setup]

**Explanation of the Reaction Diagram:**
- The diagram shows a molecule of dinitrogen tetroxide (\( \text{N}_2\text{O}_4 \)) where one oxygen atom is labeled as \( ^{18}\text{O} \).

**Question 1:**
If the equilibrium is **NOT dynamic**, the forward reaction will continue until equilibrium is reached and then cease. Under this condition, which of the structures below would be observed for \( \text{N}_2\text{O}_4 \)?

**Question 2:**
If the equilibrium **IS dynamic**, the forward and reverse reactions will continue even after equilibrium is reached. Under this condition, which of the structures below would be observed for \( \text{N}_2\text{O}_4 \)?

**Instructions:**
Put letters in alphabetical order. If none are correct, enter NONE. Do not put spaces, commas, or other characters between your answers.

**Structural Options:**

A. 
![Structural Option A: N-N bonded with one O-18 and one O]

\[
^{18}\text{O-N=N-O}
\]

B.
![Structural Option B: N-N bonded with two O-18's]

\[
^{18}\text{O-N=N-O}^{18}
\]

C.
![Structural Option C: N-N bonded with one O-18 and two O's]

\[
^{18}\text{O=N-N=O}^{18}
\]

D.
![Structural Option D: N-N bonded with two O's]

\[
\text{O=N-N=O}
\]
Transcribed Image Text:**Dynamic Equilibrium Experiment** In this experiment, we are examining the dynamic equilibrium of the reaction: \[ \text{N}_2\text{O}_4 \, (\text{g}) \rightleftharpoons \, 2 \, \text{NO}_2 \, (\text{g}) \] The goal is to demonstrate the concept of dynamic equilibrium. We start with a special form of \( \text{N}_2\text{O}_4 \) in which one of the oxygen atoms is isotopically labeled with \( ^{18}\text{O} \) instead of \( ^{16}\text{O} \). The system is then allowed to reach equilibrium. ![Image of chemical setup] **Explanation of the Reaction Diagram:** - The diagram shows a molecule of dinitrogen tetroxide (\( \text{N}_2\text{O}_4 \)) where one oxygen atom is labeled as \( ^{18}\text{O} \). **Question 1:** If the equilibrium is **NOT dynamic**, the forward reaction will continue until equilibrium is reached and then cease. Under this condition, which of the structures below would be observed for \( \text{N}_2\text{O}_4 \)? **Question 2:** If the equilibrium **IS dynamic**, the forward and reverse reactions will continue even after equilibrium is reached. Under this condition, which of the structures below would be observed for \( \text{N}_2\text{O}_4 \)? **Instructions:** Put letters in alphabetical order. If none are correct, enter NONE. Do not put spaces, commas, or other characters between your answers. **Structural Options:** A. ![Structural Option A: N-N bonded with one O-18 and one O] \[ ^{18}\text{O-N=N-O} \] B. ![Structural Option B: N-N bonded with two O-18's] \[ ^{18}\text{O-N=N-O}^{18} \] C. ![Structural Option C: N-N bonded with one O-18 and two O's] \[ ^{18}\text{O=N-N=O}^{18} \] D. ![Structural Option D: N-N bonded with two O's] \[ \text{O=N-N=O} \]
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