In an electrolytic cell, there is a mixture of the molten salts NaCl and KBr. If a current of 0. 12 amps was used, a. What substance is created at the anode? Why b. Calculate the mass of this substance created at the anode in 5.0 minutes? c. What substance is created at the cathode? Why? d. Calculate the mass of this substance created at the cathode in 2.5 hours?
In an electrolytic cell, there is a mixture of the molten salts NaCl and KBr. If a current of 0. 12 amps was used, a. What substance is created at the anode? Why b. Calculate the mass of this substance created at the anode in 5.0 minutes? c. What substance is created at the cathode? Why? d. Calculate the mass of this substance created at the cathode in 2.5 hours?
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
Related questions
Question
![**Electrolytic Cell Study: Electrolysis of Molten Salts NaCl and KBr**
This exercise examines the electrolysis of a mixture of molten salts, specifically sodium chloride (NaCl) and potassium bromide (KBr). A current of 0.12 amps is applied to the electrolytic cell. The questions and calculations below guide the understanding of the substances produced at the electrodes and their respective masses.
**Questions:**
a. **What substance is created at the anode? Why?**
b. **Calculate the mass of this substance created at the anode in 5.0 minutes.**
c. **What substance is created at the cathode? Why?**
d. **Calculate the mass of this substance created at the cathode in 2.5 hours.**
---
***Electrolysis Details:***
1. **Understanding the Anode Reaction:**
- At the anode, oxidation occurs. Bromine (Br⁻) ions from KBr and chloride (Cl⁻) ions from NaCl can be oxidized. However, Bromine has a lower oxidation potential compared to chlorine.
- **Substance at anode: Bromine (Br₂) is produced.**
2. **Mass Calculation at the Anode:**
- **Given:**
- Current (I) = 0.12 amps
- Time (t) = 5.0 minutes = 5 * 60 = 300 seconds
- Faraday's constant (F) ≈ 96485 C/mol
- Molar mass of Bromine (Br₂) ≈ 159.8 g/mol
- Number of electrons transferred (n) = 2
- **Calculation Steps:**
- Charge (Q) = Current (I) × Time (t)
\[ Q = 0.12 \, \text{amps} \times 300 \, \text{seconds} = 36 \, \text{coulombs} \]
- Moles of Br₂ (n_electrons) = \(\frac{Q}{nF}\)
\[ n_electrons = \frac{36 \, \text{C}}{2 \times 96485 \, \text{C/mol}} \approx 1.86 \times 10^{-4} \, \text{mol} \]](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fd75e31df-4f53-40d7-ad9b-050ec57c1b0b%2F0c7cffe9-64f0-4cf7-97c4-df7be1e757cd%2Fphkb9q1_processed.png&w=3840&q=75)
Transcribed Image Text:**Electrolytic Cell Study: Electrolysis of Molten Salts NaCl and KBr**
This exercise examines the electrolysis of a mixture of molten salts, specifically sodium chloride (NaCl) and potassium bromide (KBr). A current of 0.12 amps is applied to the electrolytic cell. The questions and calculations below guide the understanding of the substances produced at the electrodes and their respective masses.
**Questions:**
a. **What substance is created at the anode? Why?**
b. **Calculate the mass of this substance created at the anode in 5.0 minutes.**
c. **What substance is created at the cathode? Why?**
d. **Calculate the mass of this substance created at the cathode in 2.5 hours.**
---
***Electrolysis Details:***
1. **Understanding the Anode Reaction:**
- At the anode, oxidation occurs. Bromine (Br⁻) ions from KBr and chloride (Cl⁻) ions from NaCl can be oxidized. However, Bromine has a lower oxidation potential compared to chlorine.
- **Substance at anode: Bromine (Br₂) is produced.**
2. **Mass Calculation at the Anode:**
- **Given:**
- Current (I) = 0.12 amps
- Time (t) = 5.0 minutes = 5 * 60 = 300 seconds
- Faraday's constant (F) ≈ 96485 C/mol
- Molar mass of Bromine (Br₂) ≈ 159.8 g/mol
- Number of electrons transferred (n) = 2
- **Calculation Steps:**
- Charge (Q) = Current (I) × Time (t)
\[ Q = 0.12 \, \text{amps} \times 300 \, \text{seconds} = 36 \, \text{coulombs} \]
- Moles of Br₂ (n_electrons) = \(\frac{Q}{nF}\)
\[ n_electrons = \frac{36 \, \text{C}}{2 \times 96485 \, \text{C/mol}} \approx 1.86 \times 10^{-4} \, \text{mol} \]
Expert Solution
![](/static/compass_v2/shared-icons/check-mark.png)
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
Step by step
Solved in 3 steps with 4 images
![Blurred answer](/static/compass_v2/solution-images/blurred-answer.jpg)
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Recommended textbooks for you
![Chemistry](https://www.bartleby.com/isbn_cover_images/9781305957404/9781305957404_smallCoverImage.gif)
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
![Chemistry](https://www.bartleby.com/isbn_cover_images/9781259911156/9781259911156_smallCoverImage.gif)
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
![Principles of Instrumental Analysis](https://www.bartleby.com/isbn_cover_images/9781305577213/9781305577213_smallCoverImage.gif)
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
![Chemistry](https://www.bartleby.com/isbn_cover_images/9781305957404/9781305957404_smallCoverImage.gif)
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
![Chemistry](https://www.bartleby.com/isbn_cover_images/9781259911156/9781259911156_smallCoverImage.gif)
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
![Principles of Instrumental Analysis](https://www.bartleby.com/isbn_cover_images/9781305577213/9781305577213_smallCoverImage.gif)
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
![Organic Chemistry](https://www.bartleby.com/isbn_cover_images/9780078021558/9780078021558_smallCoverImage.gif)
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
![Chemistry: Principles and Reactions](https://www.bartleby.com/isbn_cover_images/9781305079373/9781305079373_smallCoverImage.gif)
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
![Elementary Principles of Chemical Processes, Bind…](https://www.bartleby.com/isbn_cover_images/9781118431221/9781118431221_smallCoverImage.gif)
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY