In addition to organic halides, alkyl tosylates (R′OTs) reactwith organocuprates (R2CuLi) to form coupling products R–R′. When 2°alkyl tosylates are used as starting materials (R2CHOTs), inversion of theconfiguration at a stereogenic center results. Keeping this in mind, drawthe product formed when each compound is treated with (CH3)2CuLi.

Species containing copper-carbon bonds are known as organocuprate reagents. The reaction involves…

Answered: In addition to organic halides, alkyl…

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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In addition to organic halides, alkyl tosylates (R′OTs) react
with organocuprates (R₂CuLi) to form coupling products R–R′. When 2°
alkyl tosylates are used as starting materials (R₂CHOTs), inversion of the
configuration at a stereogenic center results. Keeping this in mind, draw
the product formed when each compound is treated with (CH₃)₂CuLi.

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