In a study of the rearrangement of ammonium cyanate to urea in aqueous solution at 50 °C NH,NCO(aq)→(NH,),CO(aq) the following data were obtained: (NH,NCO], M 0.146 1.83x10 2 S.66x10 7.30x102 3.65x102 minutes 2.44x10 812 Hint: It is not necessary to graph these data, (1) The observed half life for this reaction when the starting concentration is 0.146 M is min and when the starting concentration is 7.30x10?M is min. (2) The average A(1/[NH,NCO]) / At from t=0 min to t- 812 min is The average A(1/[NH,NCO]) / At from t= 812 min to t= 2.44x10 min is MI min M' min 1. (3) Based on these data, the rate constant for this v order reaction is M min

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
In a study of the rearrangement of ammonium cyanate to urea in aqueous solution at 50 °C
NH,NCO(aq)→(NH,),CO(aq)
the following data were obtained:
(NH,NCO], M 0.146
1.83x10 2
S.66x10
7.30x102
3.65x102
minutes
2.44x10
812
Hint: It is not necessary to graph these data.
(1)
The observed half life for this reaction when the starting concentration is 0.146 M is
concentration is 7.30x102 M is
min and when the starting
min.
(2)
The average A(1/[NH,NCO]) / At from t= 0 min to t- 812 min is
The average A(1/[NH,NCO]) / At from t= 812 min to t= 2.44x103 min is
M1 min
M' min .
(3)
Based on these data, the rate constant for this
v order reaction is
M1 min !
Transcribed Image Text:In a study of the rearrangement of ammonium cyanate to urea in aqueous solution at 50 °C NH,NCO(aq)→(NH,),CO(aq) the following data were obtained: (NH,NCO], M 0.146 1.83x10 2 S.66x10 7.30x102 3.65x102 minutes 2.44x10 812 Hint: It is not necessary to graph these data. (1) The observed half life for this reaction when the starting concentration is 0.146 M is concentration is 7.30x102 M is min and when the starting min. (2) The average A(1/[NH,NCO]) / At from t= 0 min to t- 812 min is The average A(1/[NH,NCO]) / At from t= 812 min to t= 2.44x103 min is M1 min M' min . (3) Based on these data, the rate constant for this v order reaction is M1 min !
Expert Solution
steps

Step by step

Solved in 2 steps with 2 images

Blurred answer
Knowledge Booster
Dynamics of Molecular Collisions
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY