In a study of the rearrangement of ammonium cyanate to urea in aqueous solution at 50 °C NH,NCO(aq)→(NH,),CO(aq) the following data were obtained: (NH,NCO], M 0.146 1.83x10 2 S.66x10 7.30x102 3.65x102 minutes 2.44x10 812 Hint: It is not necessary to graph these data, (1) The observed half life for this reaction when the starting concentration is 0.146 M is min and when the starting concentration is 7.30x10?M is min. (2) The average A(1/[NH,NCO]) / At from t=0 min to t- 812 min is The average A(1/[NH,NCO]) / At from t= 812 min to t= 2.44x10 min is MI min M' min 1. (3) Based on these data, the rate constant for this v order reaction is M min
In a study of the rearrangement of ammonium cyanate to urea in aqueous solution at 50 °C NH,NCO(aq)→(NH,),CO(aq) the following data were obtained: (NH,NCO], M 0.146 1.83x10 2 S.66x10 7.30x102 3.65x102 minutes 2.44x10 812 Hint: It is not necessary to graph these data, (1) The observed half life for this reaction when the starting concentration is 0.146 M is min and when the starting concentration is 7.30x10?M is min. (2) The average A(1/[NH,NCO]) / At from t=0 min to t- 812 min is The average A(1/[NH,NCO]) / At from t= 812 min to t= 2.44x10 min is MI min M' min 1. (3) Based on these data, the rate constant for this v order reaction is M min
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![In a study of the rearrangement of ammonium cyanate to urea in aqueous solution at 50 °C
NH,NCO(aq)→(NH,),CO(aq)
the following data were obtained:
(NH,NCO], M 0.146
1.83x10 2
S.66x10
7.30x102
3.65x102
minutes
2.44x10
812
Hint: It is not necessary to graph these data.
(1)
The observed half life for this reaction when the starting concentration is 0.146 M is
concentration is 7.30x102 M is
min and when the starting
min.
(2)
The average A(1/[NH,NCO]) / At from t= 0 min to t- 812 min is
The average A(1/[NH,NCO]) / At from t= 812 min to t= 2.44x103 min is
M1 min
M' min .
(3)
Based on these data, the rate constant for this
v order reaction is
M1 min !](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F7cac01a1-7bc4-46f3-8025-a1c1c53c5de3%2Fb9596316-ffcf-41fe-9ecd-f0afc4a78c74%2F3kgfvda_processed.jpeg&w=3840&q=75)
Transcribed Image Text:In a study of the rearrangement of ammonium cyanate to urea in aqueous solution at 50 °C
NH,NCO(aq)→(NH,),CO(aq)
the following data were obtained:
(NH,NCO], M 0.146
1.83x10 2
S.66x10
7.30x102
3.65x102
minutes
2.44x10
812
Hint: It is not necessary to graph these data.
(1)
The observed half life for this reaction when the starting concentration is 0.146 M is
concentration is 7.30x102 M is
min and when the starting
min.
(2)
The average A(1/[NH,NCO]) / At from t= 0 min to t- 812 min is
The average A(1/[NH,NCO]) / At from t= 812 min to t= 2.44x103 min is
M1 min
M' min .
(3)
Based on these data, the rate constant for this
v order reaction is
M1 min !
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