In a study of the decomposition of ammonia on a tungsten surface at 1100 °C NH31/2 N,+3/2 H2 the concentration of NH, was followed as a function of time. It was found that a graph of [NH3] versus time in seconds gave a straight line with a slope of -4.52x10-6 M s and a y-intercept of 5.82×10³ M. Based on this plot, the reaction is order in NHz and the rate constant for the reaction is Ms.

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In a study of the decomposition of ammonia on a tungsten surface at 1100 °C:

\[ \text{NH}_3 \rightarrow \frac{1}{2} \text{N}_2 + \frac{3}{2} \text{H}_2 \]

the concentration of \(\text{NH}_3\) was followed as a function of time.

It was found that a graph of [\(\text{NH}_3\)] versus time in seconds gave a straight line with a slope of \(-4.52 \times 10^{-6} \, \text{M s}^{-1}\) and a y-intercept of \(5.82 \times 10^{-3} \, \text{M}\).

Based on this plot, the reaction is \(\boxed{\phantom{1}}\) order in \(\text{NH}_3\) and the rate constant for the reaction is \(\boxed{\phantom{1}}\ \text{M s}^{-1}\).
Transcribed Image Text:In a study of the decomposition of ammonia on a tungsten surface at 1100 °C: \[ \text{NH}_3 \rightarrow \frac{1}{2} \text{N}_2 + \frac{3}{2} \text{H}_2 \] the concentration of \(\text{NH}_3\) was followed as a function of time. It was found that a graph of [\(\text{NH}_3\)] versus time in seconds gave a straight line with a slope of \(-4.52 \times 10^{-6} \, \text{M s}^{-1}\) and a y-intercept of \(5.82 \times 10^{-3} \, \text{M}\). Based on this plot, the reaction is \(\boxed{\phantom{1}}\) order in \(\text{NH}_3\) and the rate constant for the reaction is \(\boxed{\phantom{1}}\ \text{M s}^{-1}\).
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