For the gas phase decomposition of sulfuryl chloride at 600 K SO₂Cl₂ →SO₂ + Cl₂ the following data have been obtained: [SO₂Cl₂], M 4.03x10-3 time, min 0 2.70x10-3 143 1.81x10-3 286 1.21x10-3 429 The average rate of disappearance of SO₂Cl₂ over the time period from t = 286 min to t = 429 min is M min-1.

For the gas phase decomposition of sulfuryl chloride at 600 K SO₂Cl₂ →SO₂ + Cl₂ the following data have been obtained: [SO₂Cl₂], M 4.03x10-3 time, min 0 2.70x10-3 143 1.81x10-3 286 1.21x10-3 429 The average rate of disappearance of SO₂Cl₂ over the time period from t = 286 min to t = 429 min is M min-1.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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For the decomposition of nitrous oxide at 565 °C 2 N20 2 N2 + 02 the average rate of disappearance of N20 over the time period from t 0 s to t= 1088 s is found to be 5.45×104 Ms. The average rate of formation of O, over the same time period is Ms.
For the decomposition of dinitrogen pentoxide in carbon tetrachloride solution at 30 °C 2 N₂O5 4 NO2 + O2 the average rate of disappearance of N₂O5 over the time period from t = 0 min to t = 159 min is found to be 5.79x10-4 M min¹¹. The average rate of formation of O₂ over the same time period is M min-¹.
The following data are for the gas phase decomposition of dimethyl ether at 500 °C.CH3OCH3(g) CH4(g) + H2(g) + CO(g) [ CH3OCH3 ], M 0.101 5.05×10-2 2.53×10-2 1.27×10-2 time, min 0 20.0 40.0 60.0 Hint: It is not necessary to graph these data.(1)The half life observed for this reaction is min .(2)Based on these data, the rate constant for this order reaction is min -1.
For the gas phase decomposition of hydrogen peroxide at 400 °C 2 H2O2 2 H2O + O2 the following data have been obtained: [H,O2], M 9.35x10-2 3.54x10-2 2.18×10-2 1.56x10-2 time, s 27.0 54.0 81.0 The average rate of disappearance of H,O2 over the time period from t = 27.0 s to t = 54.0 s is |Ms-!.
For the decomposition of dinitrogen pentoxide in carbon tetrachloride solution at 30 °C 2 N₂O5 → 4NO2 + O2 the following data have been obtained: [N2O5], M 0.594 0.329 0.182 0.101 time, min 0 144 288 432 The average rate of disappearance of N₂O5 over the time period from t = 0 min to t = 144 min is M/min
For the gas phase decomposition of phosphine at 120 °C 4 PH3 (9) → P4 (9)+ 6 H₂ (9) the following data have been obtained: [PH3], M time, s 0 The average rate of disappearance of PH3 over the time period from t = 0s to t = 23.0 s is 0.0644 0.0426 0.0281 0.0186 23.0 46.0 69.0 M/s.
For the gas phase decomposition of nitrogen dioxide at 383 °C2 NO2 -------> 2 NO + O2the following data have been obtained: [NO2], M 0.423 0.178 0.113 7.61x10-2 time, s 0 6.00 12.0 18.0 The average rate of disappearance of NO2 over the time period from t = 6.00 s to t = 12.0 s is ________ M s-1.
or the decomposition of nitrous oxide at 565 °C2 N2O2 N2 + O2the following data have been obtained: [N2O], M 1.48 0.463 0.274 0.195 time, s 0 22.5 45.0 67.5 The average rate of disappearance of N2O over the time period from t = 22.5 s to t = 45.0 s is M s-1.
For the gas phase decomposition of nitrosyl chloride at 400 K 2 NOCI→2 NO + Cl, the average rate of disappearance of NOCI over the time period from t = 0 s to t = 42480 s is found to be 8.69×107 M s1. The average rate of formation of Cl, over the same time period is M s1
Cindy decomposed a metal hydroxide via the reation: Mt(OH) 3 → MtO + H20, and then collected concentration and time data. After analyzing on her TI84 the following data were obtained. [Mt(OH)3] vs. time a = 2.10 x 104 In[Mt(OH)3] vs. time a = -5.80 x 10-5 b = -0.770 r = 0.999 [Mt(OH)3] vs. time a = -1.72 x 10-5 b = 0.450 r = 0.917 2.00 %3D r² 0.981 What is the order with respect to Mt(OH)3? What is the value of the rate constant for this reaction?
For the decomposition of nitrosyl bromide at 10 °C 2 NOBR 2 NO + Br2 the average rate of disappearance of NOBR over the time period from t = 0 s to t = 34 s is found to be 7.53x10 4 M s1. The average rate of formation of Br, over the same time period is Ms-1.
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