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For the gas phase decomposition of sulfuryl chloride at 600 K SO₂Cl₂ →SO₂ + Cl₂ the following data have been obtained: [SO₂Cl₂], M 4.03x10-3 time, min 0 2.70x10-3 143 1.81x10-3 286 1.21x10-3 429 The average rate of disappearance of SO₂Cl₂ over the time period from t = 286 min to t = 429 min is M min-1.

For the gas phase decomposition of sulfuryl chloride at 600 K SO₂Cl₂ →SO₂ + Cl₂ the following data have been obtained: [SO₂Cl₂], M 4.03x10-3 time, min 0 2.70x10-3 143 1.81x10-3 286 1.21x10-3 429 The average rate of disappearance of SO₂Cl₂ over the time period from t = 286 min to t = 429 min is M min-1.

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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For the gas phase decomposition of sulfuryl chloride at 600 K: \[ \text{SO}_2\text{Cl}_2 \rightarrow \text{SO}_2 + \text{Cl}_2 \] the following data have been obtained: \[ \begin{array}{|c|c|c|c|c|} \hline \text{[SO}_2\text{Cl}_2], \text{ M} & 4.03 \times 10^{-3} & 2.70 \times 10^{-3} & 1.81 \times 10^{-3} & 1.21 \times 10^{-3} \\ \hline \text{time, min} & 0 & 143 & 286 & 429 \\ \hline \end{array} \] The average rate of disappearance of \(\text{SO}_2\text{Cl}_2\) over the time period from \(t = 286 \, \text{min}\) to \(t = 429 \, \text{min}\) is \(\_\_\_\_ \, \text{M min}^{-1}\).
Transcribed Image Text:For the gas phase decomposition of sulfuryl chloride at 600 K: \[ \text{SO}_2\text{Cl}_2 \rightarrow \text{SO}_2 + \text{Cl}_2 \] the following data have been obtained: \[ \begin{array}{|c|c|c|c|c|} \hline \text{[SO}_2\text{Cl}_2], \text{ M} & 4.03 \times 10^{-3} & 2.70 \times 10^{-3} & 1.81 \times 10^{-3} & 1.21 \times 10^{-3} \\ \hline \text{time, min} & 0 & 143 & 286 & 429 \\ \hline \end{array} \] The average rate of disappearance of \(\text{SO}_2\text{Cl}_2\) over the time period from \(t = 286 \, \text{min}\) to \(t = 429 \, \text{min}\) is \(\_\_\_\_ \, \text{M min}^{-1}\).
For the gas phase decomposition of hydrogen peroxide at 400 °C \[2 \text{H}_2\text{O}_2 \rightarrow 2 \text{H}_2\text{O} + \text{O}_2\] the following data have been obtained: \[ \begin{array}{|c|c|c|c|c|} \hline [\text{H}_2\text{O}_2], \text{M} & 0.108 & 3.56 \times 10^{-2} & 2.13 \times 10^{-2} & 1.50 \times 10^{-2} \\ \hline \text{time, s} & 0 & 29.0 & 58.0 & 87.0 \\ \hline \end{array} \] The average rate of disappearance of \[\text{H}_2\text{O}_2\] over the time period from \( t = 29.0 \, \text{s} \) to \( t = 58.0 \, \text{s} \) is \(\_\_\_\_\) M s\(^{-1}\).
Transcribed Image Text:For the gas phase decomposition of hydrogen peroxide at 400 °C \[2 \text{H}_2\text{O}_2 \rightarrow 2 \text{H}_2\text{O} + \text{O}_2\] the following data have been obtained: \[ \begin{array}{|c|c|c|c|c|} \hline [\text{H}_2\text{O}_2], \text{M} & 0.108 & 3.56 \times 10^{-2} & 2.13 \times 10^{-2} & 1.50 \times 10^{-2} \\ \hline \text{time, s} & 0 & 29.0 & 58.0 & 87.0 \\ \hline \end{array} \] The average rate of disappearance of \[\text{H}_2\text{O}_2\] over the time period from \( t = 29.0 \, \text{s} \) to \( t = 58.0 \, \text{s} \) is \(\_\_\_\_\) M s\(^{-1}\).
Expert Solution
Step 1: Defining the average rate of disappearance!

Answer:

The average rate of disappearance is equal to the change in concentration of the reactant with respect to time, so

straight r subscript avg equals negative fraction numerator increment straight C over denominator increment straight t end fraction

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