Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:If the E 0.023 V versus. S.CE, what is the cell potential versus a Ag ABCI?
ell
-0.266
O b. 0.415
C.
0.266 V
O d.-0415 V
O e -0.021
The most widely used potassium selective membrane electrode employs the antibiotic valinomycin as an ionophore within a thin polymeric
membrane at the distal end of the electrode. The presence of valinomycin enables the organic membrane to exhibit a voltage (EMF) that is
highly dependent on the potassium activity in the sample, with relatively little interference from other common cations. The function of the
valinomycin in this system is to:
Select one:
O a. Sequester/bind all other cations present in the sample thus allowing only potassium to enter the membrane
O b. Selectively binds potassium to form a valinomycin/potassium complexwithin the membrane phase
Oc. Serves as an anionic site within the membrane to neutralize the charge of potassium
O d. Selectively binds sodium and other group I metals to form a valinomycin/metal complex within the membrane phase
O e. None of the above
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