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Identify the major and minor product(s) of the following reaction: A. OH conc. H,50 Heat Major product(s): OH ? B. Identify the major and minor product(s) of the following reaction: C. Identify the major and minor product(s) of the following reaction: NaOEt NICH ? ? Major product(s): रा eTextbook and Media eTextbook and Media Minor product(s): Minor product(s): @ Oth OH Major product(s): EtO (racemic) eTextbook and Media Minor product(s): D. There are two stereoisomers of 1-tert-butyl-4-chloro-cyclohexane. One of these isomers reacts with sodium ethoxide in an E2 reaction that is 500 times faster than the reaction of the other isomer. Identify the isomer that reacts faster, and explain the difference in rate for these two isomers. fizi The an isomer rapidly undergoes an E2 reaction because it is locked in a chair conformation in which the chlorine occupies position, as shown in drawing antiperiplanar to a beta proton. Because of the bulky tert-butyl group, the and the leaving group -isomer is essentially locked in a chair conformation in which the chlorine occupies an position, as shown in drawing and the leaving group is not antiperiplanar to a beta proton. EtO (racemic)

Identify the major and minor product(s) of the following reaction: A. OH conc. H,50 Heat Major product(s): OH ? B. Identify the major and minor product(s) of the following reaction: C. Identify the major and minor product(s) of the following reaction: NaOEt NICH ? ? Major product(s): रा eTextbook and Media eTextbook and Media Minor product(s): Minor product(s): @ Oth OH Major product(s): EtO (racemic) eTextbook and Media Minor product(s): D. There are two stereoisomers of 1-tert-butyl-4-chloro-cyclohexane. One of these isomers reacts with sodium ethoxide in an E2 reaction that is 500 times faster than the reaction of the other isomer. Identify the isomer that reacts faster, and explain the difference in rate for these two isomers. fizi The an isomer rapidly undergoes an E2 reaction because it is locked in a chair conformation in which the chlorine occupies position, as shown in drawing antiperiplanar to a beta proton. Because of the bulky tert-butyl group, the and the leaving group -isomer is essentially locked in a chair conformation in which the chlorine occupies an position, as shown in drawing and the leaving group is not antiperiplanar to a beta proton. EtO (racemic)

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Identify the major and minor product(s) of the following reaction: A. OH conc. H,50 Heat Major product(s): OH ? B. Identify the major and minor product(s) of the following reaction: C. Identify the major and minor product(s) of the following reaction: NaOEt NICH ? ? Major product(s): रा eTextbook and Media eTextbook and Media Minor product(s): Minor product(s): @ Oth OH Major product(s): EtO (racemic) eTextbook and Media Minor product(s): D. There are two stereoisomers of 1-tert-butyl-4-chloro-cyclohexane. One of these isomers reacts with sodium ethoxide in an E2 reaction that is 500 times faster than the reaction of the other isomer. Identify the isomer that reacts faster, and explain the difference in rate for these two isomers. fizi The an isomer rapidly undergoes an E2 reaction because it is locked in a chair conformation in which the chlorine occupies position, as shown in drawing antiperiplanar to a beta proton. Because of the bulky tert-butyl group, the and the leaving group -isomer is essentially locked in a chair conformation in which the chlorine occupies an position, as shown in drawing and the leaving group is not antiperiplanar to a beta proton. EtO (racemic)
Transcribed Image Text:Identify the major and minor product(s) of the following reaction: A. OH conc. H,50 Heat Major product(s): OH ? B. Identify the major and minor product(s) of the following reaction: C. Identify the major and minor product(s) of the following reaction: NaOEt NICH ? ? Major product(s): रा eTextbook and Media eTextbook and Media Minor product(s): Minor product(s): @ Oth OH Major product(s): EtO (racemic) eTextbook and Media Minor product(s): D. There are two stereoisomers of 1-tert-butyl-4-chloro-cyclohexane. One of these isomers reacts with sodium ethoxide in an E2 reaction that is 500 times faster than the reaction of the other isomer. Identify the isomer that reacts faster, and explain the difference in rate for these two isomers. fizi The an isomer rapidly undergoes an E2 reaction because it is locked in a chair conformation in which the chlorine occupies position, as shown in drawing antiperiplanar to a beta proton. Because of the bulky tert-butyl group, the and the leaving group -isomer is essentially locked in a chair conformation in which the chlorine occupies an position, as shown in drawing and the leaving group is not antiperiplanar to a beta proton. EtO (racemic)
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