Identify each of the following reactions types SCH3 Br H J. F. + + محمد NaSCH; OH Ethanol NHẠCH H -OCH3 © CH3 H₂C-CH₂ 0₂₁₂ H₂SO4 heat H3C of You - OH + NH₂ to CH3 OH Acetic acid (Vinegar is 5% acetic acid in water) NaBr

World of Chemistry, 3rd edition
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Chapter20: Organic Chemistry
Section: Chapter Questions
Problem 21A
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**Identify Each of the Following Reaction Types**

1. **First Reaction:**
   - **Type:** Dehydrohalogenation
   - **Reactants:** Cyclohexyl bromide and a base
   - **Products:** Cyclohexene and HBr
   - **Description:** The hydrogen atom and the bromine atom are removed from the adjacent carbon atoms, resulting in the formation of a double bond and cyclohexene.

2. **Second Reaction:**
   - **Type:** Nucleophilic Substitution (SN2)
   - **Reactants:** Cyclohexyl bromide and sodium thiomethoxide (NaSCH3)
   - **Products:** Cyclohexyl methyl sulfide and sodium bromide
   - **Description:** The bromine atom is replaced by a methoxysulfide group (-SCH3).

3. **Third Reaction:**
   - **Type:** Ammonolysis
   - **Reactants:** Butanone and ammonium chloride (NH4Cl)
   - **Products:** Butylammonium chloride and ammonia (NH3)
   - **Description:** The ketone reacts with ammonia forming a primary amine.

4. **Fourth Reaction:**
   - **Type:** Dehydration
   - **Reactants:** Alcohol and sulfuric acid (H2SO4) with heat
   - **Products:** Alkene
   - **Description:** Removal of water (H2O) from 3-methyl-2-pentanol produces an alkene (3-methyl-1-pentene).

5. **Fifth Reaction:**
   - **Type:** Oxidation
   - **Reactants:** Ethanol and oxygen (O2)
   - **Products:** Acetic acid
   - **Description:** Ethanol is oxidized to acetic acid, which is a major component of vinegar.

6. **Sixth Reaction:**
   - **Type:** Hydrogenation
   - **Reactants:** Alkene and hydrogen (H2) with Lindlar catalyst
   - **Products:** Alkane
   - **Description:** The triple bond is partially reduced to a double bond due to the Lindlar catalyst, resulting in partial hydrogenation of alkyne to alkene.

7. **Seventh Reaction:**
   - **Type:** Halogenation
   - **Reactants:** Cyclopentene and chlorine (Cl2
Transcribed Image Text:**Identify Each of the Following Reaction Types** 1. **First Reaction:** - **Type:** Dehydrohalogenation - **Reactants:** Cyclohexyl bromide and a base - **Products:** Cyclohexene and HBr - **Description:** The hydrogen atom and the bromine atom are removed from the adjacent carbon atoms, resulting in the formation of a double bond and cyclohexene. 2. **Second Reaction:** - **Type:** Nucleophilic Substitution (SN2) - **Reactants:** Cyclohexyl bromide and sodium thiomethoxide (NaSCH3) - **Products:** Cyclohexyl methyl sulfide and sodium bromide - **Description:** The bromine atom is replaced by a methoxysulfide group (-SCH3). 3. **Third Reaction:** - **Type:** Ammonolysis - **Reactants:** Butanone and ammonium chloride (NH4Cl) - **Products:** Butylammonium chloride and ammonia (NH3) - **Description:** The ketone reacts with ammonia forming a primary amine. 4. **Fourth Reaction:** - **Type:** Dehydration - **Reactants:** Alcohol and sulfuric acid (H2SO4) with heat - **Products:** Alkene - **Description:** Removal of water (H2O) from 3-methyl-2-pentanol produces an alkene (3-methyl-1-pentene). 5. **Fifth Reaction:** - **Type:** Oxidation - **Reactants:** Ethanol and oxygen (O2) - **Products:** Acetic acid - **Description:** Ethanol is oxidized to acetic acid, which is a major component of vinegar. 6. **Sixth Reaction:** - **Type:** Hydrogenation - **Reactants:** Alkene and hydrogen (H2) with Lindlar catalyst - **Products:** Alkane - **Description:** The triple bond is partially reduced to a double bond due to the Lindlar catalyst, resulting in partial hydrogenation of alkyne to alkene. 7. **Seventh Reaction:** - **Type:** Halogenation - **Reactants:** Cyclopentene and chlorine (Cl2
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