Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question
Indicate the peaks of this spectrum using the table
Transcribed Image Text:May
ID00
3000
2000
1S00
1000
HVENUHEERIl
Transcribed Image Text:Simplified Infrared Correlation Chart
Type of Vibration
(stretch)
Frequency (cm")
Intensity
C-H
Alkanes
3000-2850
-CH
-CH
(bend)
(bend)
1450 and 1375
1465
m
Alkenes
(stretch)
3100-3000
(out-of-plane bend)
1000-650
Aromatics
(stretch)
3150-3050
(out-of-plane bend)
(stretch)
900-690
Alkyne
-3300
Aldehyde
2900-2800
2800-2700
C-C
Alkane
not interpretatively useful
C=C
Alkene
1680-1600
m-w
Aromatic
1600 and 1475
m-w
Alkyne
2250-2100
m-w
C=0
Aldehyde
1740-1720
Ketone
1725-1705
Carboxylic Acid
1725-1700
Ester
1750-1730
Amide
1670-1640
1810 and 1760
Anhydride
Acid Chloride
1800
C-O
Alcohols, Ethers, Esters, Carboxylic Acids, Anhydrides 1300-1000
O-H
Alcohols, Phenols
Free
3650-3600
m
H-bonded
3500-3200
m
Carboxylic Acids
3400-2400
N-H
Primary and Secondary Amines and Amides
(stretch)
3500-3100
(bend)
1640-1550
m-s
C-N
Amines
1350-1000
m-s
C=N
Imines and Oximes
1690-1640
w-S
CEN
Nitriles
2260-2240
X=C=Y
Allenes, Ketenes, Isocyanates, Isothiocyanates
2270-1950
m-s
N=O
Nitro (R-NO2)
1550 and 1350
S-H
Mercaptans
2550
S-O
Sulfoxides
1050
Sulfones, Sulfonyl Chlorides, Sulfates, Sulfonamides
1375-1300 and
1200-1140
C-X
Fluoride
1400-1000
Chloride
800-600
Bromide, lodide
<667
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