### Elimination Reactions1. **For the following elimination reactions:** (i) Write the bond-line structure of the substrate and the reagent. (ii) Write the full mechanism for the reaction, including the transition state for E2 or the intermediate for E1. Name the reaction as either E1 or E2. (iii) Write all possible products of the reaction, defining which product(s) is/are major and which is/are minor. (iv) Name the products of the reaction if requested. **i.** When 2-iodo-1,1,2,3,3-pentamethylcyclohexane is heated in the presence of sodium ethoxide in ethanol, do not name the product(s) of the reaction.**j.**Reaction: **3-bromo-2,2,3,5-tetramethylhexane** Reagents: **tert-BuOK, tert-BuOH** Reaction proceeds to the right (indicated by an arrow).**Explanation of Diagrams:**In section j, the reactant, 3-bromo-2,2,3,5-tetramethylhexane, undergoes a reaction with tert-butoxide (tert-BuOK) and tert-butanol (tert-BuOH) as reagents. The arrow pointing to the right indicates the direction of the reaction. No products are shown, leaving it up to the learner to determine the outcome based on the reaction conditions described.

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i. 2-iodo-1,1,2,3,3-pentamethylcyclohexane is heated in the presence of sodium ethoxide in ethanol, don't name the product/s of the reaction j. tert-BUOK, tert-BUOH 3-bromo-2,2,3,5-tetramethylhexane

Chemistry

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ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

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### Elimination Reactions

1. **For the following elimination reactions:**

(i) Write the bond-line structure of the substrate and the reagent.

(ii) Write the full mechanism for the reaction, including the transition state for E2 or the intermediate for E1. Name the reaction as either E1 or E2.

(iii) Write all possible products of the reaction, defining which product(s) is/are major and which is/are minor.

(iv) Name the products of the reaction if requested.

**i.** When 2-iodo-1,1,2,3,3-pentamethylcyclohexane is heated in the presence of sodium ethoxide in ethanol, do not name the product(s) of the reaction.

**j.**

Reaction: **3-bromo-2,2,3,5-tetramethylhexane**
Reagents: **tert-BuOK, tert-BuOH**
Reaction proceeds to the right (indicated by an arrow).

**Explanation of Diagrams:**

In section j, the reactant, 3-bromo-2,2,3,5-tetramethylhexane, undergoes a reaction with tert-butoxide (tert-BuOK) and tert-butanol (tert-BuOH) as reagents. The arrow pointing to the right indicates the direction of the reaction. No products are shown, leaving it up to the learner to determine the outcome based on the reaction conditions described.

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