I Review | Constants | Periodic Table Average Bond Enthalpies (kJ/mol) Part A C-H 413 N-H 391 O-H 463 F-F 155 C-C 348 N-N 163 O-0 146 Consider the reaction between chloromethane (CH;CI) and water in the gas phase to form methanol (CH,OH) and hydrogen chloride: C=C_614 N–0 201 O=0 95 Cl-F 253 C-N 293 N-F 272 0-F 190 Cl–Cl 242 C-0 358 N–Cl 200 O-Cl 203 Br-F 237 234 Br-Cl 218 Br-Br 193 H H-C-CI + H–0-H → H-C-0-H + H–Cl C=0 799 N-Br 243 O-I H. H C-F 485 H-H 436 C-CI 328 H-F 567 Using the bond enthalpy data in the table, estimate the enthalpy change for this reaction. C-Br 276 H-Cl 431 C-I 240 H-Br 366 I-Cl 208 I-Br 175 I-I 151 н1 299 +465 kJ -461 kJ +2 kJ -439 kJ
Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
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Chloromethane Enthalpy of Form x
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Syllabus
I Review | Constants | Periodic Table
Scores
Average Bond Enthalpies (kJ/mol)
Pearson eText
Part A
C-H 413 N-H 391 0-H 463 F-F 155
C-C 348 N-N 163 0-0 146
C=C 614 N-0 201 0=0 4 95 Cl-F
C-N 293 N-F 272 0-F 190 Cl-Cl 242
Study Area
Consider the reaction between chloromethane (CH,CI) and water in the gas phase to form methanol
253
(CH3OH) and hydrogen chloride:
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H
H
C-0 358 N-CI 200 0-C1 203 Br-F 237
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Н—С—С
+ Н—0— Н ——
Н-—С—0- Н + Н—CI
C=0 799 N-Br 243 0-I
234 Br-Cl 218
H
H
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>
C-F
485 H-H 436
Br-Br 193
C-C1 328 H-F 567
Using the bond enthalpy data in the table, estimate the enthalpy change for this reaction.
C-Br 276 H-CI 431
I-CI 208
C-I 240 H-Br 366
I-Br 175
H-I
299
I-I
151
+465 kJ
-461 kJ
+2 kJ
-439 kJ
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