Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
Related questions
Question
I need help with 6 through 10, and I think it's all supposed to be in three sig figs. Can you help me with this?
![3-6: Heat of Combustion: Sugar
The heat of combustion (AHcomb) is the heat of reaction for the complete burning (reacting with O2) of one
mole of a substance to form CO, and H,O. Calorimetry experiments that measure the heat of combustion
can be performed at constant volume using a device called a bomb calorimeter. In a bomb calorimeter a
sample is burned in a constant-volume chamber in the presence of oxygen at high pressure. The heat that
is released warms the water surrounding the chamber. By measuring the temperature increase of the
water, it is possible to calculate the quantity of heat released during the combustion reaction. In this
assignment you will calculate the heat of combustion of sugar (sucrose, C12H22O11). The calorimeter has
already been calibrated by combusting benzoic acid.
1. Start Virtual ChemLab, select Thermodynamics, and then select Heat of Combustion: Sugar from the
list of assignments. The lab will open in the Calorimetry laboratory with the bomb calorimeter out
and disassembled and with a sample of sugar in the calorimeter cup on the balance. The balance has
already been tared.
2. Record the mass of the sugar sample from the balance. If you cannot read it, click on the Balance
area to zoom in, record the mass in the data table below and return to the laboratory.
3. Double-click the following (in numerical order) to assemble the calorimeter: (1) the cup on the
balance pan, (2) the bomb head, (3) the screw cap, and (4) the bomb. Click the calorimeter lid to close
it. Combustion experiments can take a considerable length of time. Click the clock on the wall labeled
Accelerate to accelerate the laboratory time.
4. Click the bomb control panel and the plot window to bring them to the front. Click on the Save button
to save data to the lab book. Allow the graph to proceed for 20-30 seconds to establish a baseline
temperature.
5. Click Ignite and observe the graph. When the temperature has leveled off (up to 5 minutes of
laboratory time), click Stop. A data link icon will appear in the lab book. Click the data link icon to
view the collected data. Record the temperature before and after ignition of the sugar sample in the
data table.
Data Table
sucrose (C12H2½O11)
0.9715g
mass of sample (g)
initial temperature (°C)
24.996
final temperature (°C)
26.518
6. Write a complete balanced chemical equation for the combustion of sucrose.
7. Calculate AT for the water using AT = |T;- T|.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F63e2e494-b56f-474b-94e6-a1b0d865891f%2F54fbbaa7-16c5-4aa5-810c-dc1458c6d107%2Fwkci30r_processed.png&w=3840&q=75)
Transcribed Image Text:3-6: Heat of Combustion: Sugar
The heat of combustion (AHcomb) is the heat of reaction for the complete burning (reacting with O2) of one
mole of a substance to form CO, and H,O. Calorimetry experiments that measure the heat of combustion
can be performed at constant volume using a device called a bomb calorimeter. In a bomb calorimeter a
sample is burned in a constant-volume chamber in the presence of oxygen at high pressure. The heat that
is released warms the water surrounding the chamber. By measuring the temperature increase of the
water, it is possible to calculate the quantity of heat released during the combustion reaction. In this
assignment you will calculate the heat of combustion of sugar (sucrose, C12H22O11). The calorimeter has
already been calibrated by combusting benzoic acid.
1. Start Virtual ChemLab, select Thermodynamics, and then select Heat of Combustion: Sugar from the
list of assignments. The lab will open in the Calorimetry laboratory with the bomb calorimeter out
and disassembled and with a sample of sugar in the calorimeter cup on the balance. The balance has
already been tared.
2. Record the mass of the sugar sample from the balance. If you cannot read it, click on the Balance
area to zoom in, record the mass in the data table below and return to the laboratory.
3. Double-click the following (in numerical order) to assemble the calorimeter: (1) the cup on the
balance pan, (2) the bomb head, (3) the screw cap, and (4) the bomb. Click the calorimeter lid to close
it. Combustion experiments can take a considerable length of time. Click the clock on the wall labeled
Accelerate to accelerate the laboratory time.
4. Click the bomb control panel and the plot window to bring them to the front. Click on the Save button
to save data to the lab book. Allow the graph to proceed for 20-30 seconds to establish a baseline
temperature.
5. Click Ignite and observe the graph. When the temperature has leveled off (up to 5 minutes of
laboratory time), click Stop. A data link icon will appear in the lab book. Click the data link icon to
view the collected data. Record the temperature before and after ignition of the sugar sample in the
data table.
Data Table
sucrose (C12H2½O11)
0.9715g
mass of sample (g)
initial temperature (°C)
24.996
final temperature (°C)
26.518
6. Write a complete balanced chemical equation for the combustion of sucrose.
7. Calculate AT for the water using AT = |T;- T|.
![8. Calculate the moles of sucrose in the sample (MWguerose = 342.3 g/mol).
9. AHcomb for sucrose can be calculated using AH0omb
= (C,ystem AT)/n , where n is the moles of sucrose in
´system
the sample and Csystem is the heat capacity of the calorimetric system.
Use 10.310 kJ/K for Cystem and calculate the heat of combustion, in kJ/mol, for sucrose.
10. If the accepted value for the heat of combustion for sugar is 5639 kJ/mol calculate the percent error.
|your answer – accepted answer|
-× 100
% Error
accepted answer
% Error =
This experiment does not consider that all of the conditions are standard state conditions; therefore,
you are calculating AHcomb not AH°comb.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F63e2e494-b56f-474b-94e6-a1b0d865891f%2F54fbbaa7-16c5-4aa5-810c-dc1458c6d107%2Fg2t7sun_processed.png&w=3840&q=75)
Transcribed Image Text:8. Calculate the moles of sucrose in the sample (MWguerose = 342.3 g/mol).
9. AHcomb for sucrose can be calculated using AH0omb
= (C,ystem AT)/n , where n is the moles of sucrose in
´system
the sample and Csystem is the heat capacity of the calorimetric system.
Use 10.310 kJ/K for Cystem and calculate the heat of combustion, in kJ/mol, for sucrose.
10. If the accepted value for the heat of combustion for sugar is 5639 kJ/mol calculate the percent error.
|your answer – accepted answer|
-× 100
% Error
accepted answer
% Error =
This experiment does not consider that all of the conditions are standard state conditions; therefore,
you are calculating AHcomb not AH°comb.
Expert Solution
![](/static/compass_v2/shared-icons/check-mark.png)
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
This is a popular solution!
Trending now
This is a popular solution!
Step by step
Solved in 2 steps with 2 images
![Blurred answer](/static/compass_v2/solution-images/blurred-answer.jpg)
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Recommended textbooks for you
![Chemistry](https://www.bartleby.com/isbn_cover_images/9781305957404/9781305957404_smallCoverImage.gif)
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
![Chemistry](https://www.bartleby.com/isbn_cover_images/9781259911156/9781259911156_smallCoverImage.gif)
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
![Principles of Instrumental Analysis](https://www.bartleby.com/isbn_cover_images/9781305577213/9781305577213_smallCoverImage.gif)
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
![Chemistry](https://www.bartleby.com/isbn_cover_images/9781305957404/9781305957404_smallCoverImage.gif)
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
![Chemistry](https://www.bartleby.com/isbn_cover_images/9781259911156/9781259911156_smallCoverImage.gif)
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
![Principles of Instrumental Analysis](https://www.bartleby.com/isbn_cover_images/9781305577213/9781305577213_smallCoverImage.gif)
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
![Organic Chemistry](https://www.bartleby.com/isbn_cover_images/9780078021558/9780078021558_smallCoverImage.gif)
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
![Chemistry: Principles and Reactions](https://www.bartleby.com/isbn_cover_images/9781305079373/9781305079373_smallCoverImage.gif)
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
![Elementary Principles of Chemical Processes, Bind…](https://www.bartleby.com/isbn_cover_images/9781118431221/9781118431221_smallCoverImage.gif)
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY