(i) HOCH₂CH₂CH₂-C-OH Br CH₂CH₂ H H+ (1) Mg, ether (2) CO₂ (3) H3O+ (cyclic ester) (h) (j) COOH CH3 KMnO4, H₂O (hot, concd.) butan-2-ol, H+

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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Can you propose a mechanism for the problems h,i, and j? I've also included the answers for the products that the reactions make, I'm just confused with the mechanisms.

(i)
COOH
COOH
CHO
CH₂CH3
Aqueous acid also
removes the acetal.
(j)
Ph
CH₂CH₂-CHCH₂OH
CH3
'&
60
(h)
COOH
COOH
Transcribed Image Text:(i) COOH COOH CHO CH₂CH3 Aqueous acid also removes the acetal. (j) Ph CH₂CH₂-CHCH₂OH CH3 '& 60 (h) COOH COOH
(g)
(i)
HOCH₂CH₂CH₂-C-OH
Br
CH₂CH₂ H
H+
(1) Mg, ether
(2) CO₂
(3) H₂O+
(cyclic ester)
(h)
(j)
COOH
CH3
KMnO4, H₂O
(hot, concd.)
butan-2-ol, H+
Transcribed Image Text:(g) (i) HOCH₂CH₂CH₂-C-OH Br CH₂CH₂ H H+ (1) Mg, ether (2) CO₂ (3) H₂O+ (cyclic ester) (h) (j) COOH CH3 KMnO4, H₂O (hot, concd.) butan-2-ol, H+
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