I 16 17 1. Explain why cyclopentadiene (pKa = 15) is more acidic than pyrrole (pKa = 17) even though nitrogen is more electronegative than carbon? %3D

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
Urgent
2: 3
9
10
11 12 13
14
| 15
17 1
16
1. Explain why cyclopentadiene (pKa = 15) is more acidic than pyrrole (pKa = 17) even though
nitrogen is more electronegative than carbon?
2. Why carboxylic acid with a carbonyl group at 3rd position can be decarboxylated?
3. Differentiate between Aldol and Claisen condensation reaction.
4. Explain why electrophilic aromatic substitution in Pyrrole takes place at C-2 positions
whereas, in Pyridine it takes place at C-3 position?
5. LDA is the base of choice for carbonyl compound to completely convert into enolate. Why?
6. List the following esters in order of decreasing reactivities towards hydrolysis with reason:
Methyl benzoate, p-cyano methyl benzoate and p-hydroxy methyl benzoate
!
Transcribed Image Text:2: 3 9 10 11 12 13 14 | 15 17 1 16 1. Explain why cyclopentadiene (pKa = 15) is more acidic than pyrrole (pKa = 17) even though nitrogen is more electronegative than carbon? 2. Why carboxylic acid with a carbonyl group at 3rd position can be decarboxylated? 3. Differentiate between Aldol and Claisen condensation reaction. 4. Explain why electrophilic aromatic substitution in Pyrrole takes place at C-2 positions whereas, in Pyridine it takes place at C-3 position? 5. LDA is the base of choice for carbonyl compound to completely convert into enolate. Why? 6. List the following esters in order of decreasing reactivities towards hydrolysis with reason: Methyl benzoate, p-cyano methyl benzoate and p-hydroxy methyl benzoate !
Expert Solution
steps

Step by step

Solved in 4 steps with 2 images

Blurred answer
Knowledge Booster
Green Chemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY