Hydrocyanic acid has a Ka value of 4.9 x 10-10. If the initial concentration of HCN is 0.432 M determine the pOH of this solution at equilibrium.
Hydrocyanic acid has a Ka value of 4.9 x 10-10. If the initial concentration of HCN is 0.432 M determine the pOH of this solution at equilibrium.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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![### Determining the pOH of a Hydrocyanic Acid Solution
**Problem Statement:**
Hydrocyanic acid (HCN) has a \( K_a \) value of \( 4.9 \times 10^{-10} \). If the initial concentration of HCN is 0.432 M, determine the pOH of this solution at equilibrium.
---
**Solution Steps:**
1. **Write the ionization equation for HCN:**
\[
\text{HCN} \, \rightleftharpoons \, \text{H}^+ + \text{CN}^-
\]
2. **Set up the expression for the acid dissociation constant \( K_a \):**
\[
K_a = \frac{[\text{H}^+][\text{CN}^-]}{[\text{HCN}]}
\]
Given \( K_a = 4.9 \times 10^{-10} \) and initial [HCN] = 0.432 M.
3. **Assume \( x \) is the concentration of \( \text{H}^+ \) and \( \text{CN}^- \) at equilibrium:**
\[
K_a = \frac{x^2}{0.432 - x} \approx \frac{x^2}{0.432}
\]
4. **Solve for \( x \):**
\[
x^2 = 4.9 \times 10^{-10} \times 0.432
\]
Calculate \( x \), which represents \( [\text{H}^+] \).
5. **Calculate the pH:**
\[
\text{pH} = -\log[\text{H}^+]
\]
6. **Find pOH using the relation:**
\[
\text{pOH} = 14 - \text{pH}
\]
This step-by-step guide helps in determining the equilibrium pOH of a weak acid solution using its dissociation constant and initial concentration.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F22076770-2d32-402c-bf73-75824c1d755e%2Fb908725f-02e8-4066-b651-9cb23b6cf073%2Fswq4x7r_processed.jpeg&w=3840&q=75)
Transcribed Image Text:### Determining the pOH of a Hydrocyanic Acid Solution
**Problem Statement:**
Hydrocyanic acid (HCN) has a \( K_a \) value of \( 4.9 \times 10^{-10} \). If the initial concentration of HCN is 0.432 M, determine the pOH of this solution at equilibrium.
---
**Solution Steps:**
1. **Write the ionization equation for HCN:**
\[
\text{HCN} \, \rightleftharpoons \, \text{H}^+ + \text{CN}^-
\]
2. **Set up the expression for the acid dissociation constant \( K_a \):**
\[
K_a = \frac{[\text{H}^+][\text{CN}^-]}{[\text{HCN}]}
\]
Given \( K_a = 4.9 \times 10^{-10} \) and initial [HCN] = 0.432 M.
3. **Assume \( x \) is the concentration of \( \text{H}^+ \) and \( \text{CN}^- \) at equilibrium:**
\[
K_a = \frac{x^2}{0.432 - x} \approx \frac{x^2}{0.432}
\]
4. **Solve for \( x \):**
\[
x^2 = 4.9 \times 10^{-10} \times 0.432
\]
Calculate \( x \), which represents \( [\text{H}^+] \).
5. **Calculate the pH:**
\[
\text{pH} = -\log[\text{H}^+]
\]
6. **Find pOH using the relation:**
\[
\text{pOH} = 14 - \text{pH}
\]
This step-by-step guide helps in determining the equilibrium pOH of a weak acid solution using its dissociation constant and initial concentration.
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