H₂S to 25.00 mL of acidified standard 0.010 44 M 15 to precip tate elemental sulfur. (If [H₂S]> 0.01 M. then precipitated sulf traps some I solution, which is not subsequently titrated.) T remaining I was titrated with 14.44 mL of 0.009 336 M Na₂S₂C Find the molarity of the H₂S solution. Should starch indicator added to this titration at the beginning or just before the en point?

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter16: Applications Of Neutralization Titrations
Section: Chapter Questions
Problem 16.40QAP
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16-26. H₂S was measured by slowly adding 25.00 mL of aqueous
H₂S to 25.00 mL of acidified standard 0.010 44 M 15 to precipi-
tate elemental sulfur. (If [H₂S]> 0.01 M. then precipitated sulfur
traps some I solution, which is not subsequently titrated.) The
remaining I was titrated with 14.44 mL of 0.009 336 M Na₂S₂O₂.
Find the molarity of the H₂S solution. Should starch indicator be
added to this titration at the beginning or just before the end
point?
Transcribed Image Text:16-26. H₂S was measured by slowly adding 25.00 mL of aqueous H₂S to 25.00 mL of acidified standard 0.010 44 M 15 to precipi- tate elemental sulfur. (If [H₂S]> 0.01 M. then precipitated sulfur traps some I solution, which is not subsequently titrated.) The remaining I was titrated with 14.44 mL of 0.009 336 M Na₂S₂O₂. Find the molarity of the H₂S solution. Should starch indicator be added to this titration at the beginning or just before the end point?
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