How many signals are greater than 100 ppm in the 13C NMR?  How many signals are less than 100 ppm in the 13C NMR?     How many total signals in the 13C NMR?

Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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How many signals are greater than 100 ppm in the 13C NMR? 

How many signals are less than 100 ppm in the 13C NMR?    

How many total signals in the 13C NMR?    

 
 
 
 
Expert Solution
Chemical shift value:

The chemical shift in 13c NMR :

RCH= 10- 15 ppm

R2CH= 16 - 25 ppm 

R3CH = 25- 35 ppm  

Factor affecting the chemical shift value is electonegetivity , if any electronegative atom is present in molecule it Deshiled the proton of 13 C carbon an as a result chemical shift value is increase from normal one. In given examples oxygen atom is present which show heigh electonegetivity.

 

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