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Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Draw the major product of the following reaction sequence.

The image depicts a chemical reaction involving an organosulfur compound. Here's a detailed description: **Chemical Structures:** 1. **Reactant 1:** - A thiol compound with an isopropyl group attached to the sulfur (SH) group. - Structural formula: \( \text{(CH}_3\text{)_2CHSH} \). 2. **Reagent:** - Hydroxide ion (OH⁻), indicating a basic environment. 3. **Reactant 2:** - A compound with a benzene ring directly attached to an ethyl group, linked through a sulfonate ester group (EtO-SO2). - Structural formula of the sulfonate ester includes \( \text{O=SO}_2-\text{O} \), with the ethyl group connected to the oxygen and the benzene ring connected to the sulfur. **Reaction Description:** - The reaction involves the thiolate anion (formed from the thiol and hydroxide ion) potentially attacking the sulfonate ester. This suggests a nucleophilic substitution reaction, where the sulfur atom can displace the ethyl group from the sulfonate, likely forming an alkyl thioether compound and releasing the sulfonate group. **Diagram Explanation:** - **Arrows:** - A single-headed arrow indicates the progression of the reaction from the reactants (thiol and sulfonate) in the presence of base (OH⁻). It shows the transformation into the corresponding products, not depicted, under the influence of these reactants and conditions. This reaction setup exemplifies typical nucleophilic substitutions in organic chemistry, demonstrating the reactivity of thiolates with suitable leaving groups like sulfonates.
Transcribed Image Text:The image depicts a chemical reaction involving an organosulfur compound. Here's a detailed description: **Chemical Structures:** 1. **Reactant 1:** - A thiol compound with an isopropyl group attached to the sulfur (SH) group. - Structural formula: \( \text{(CH}_3\text{)_2CHSH} \). 2. **Reagent:** - Hydroxide ion (OH⁻), indicating a basic environment. 3. **Reactant 2:** - A compound with a benzene ring directly attached to an ethyl group, linked through a sulfonate ester group (EtO-SO2). - Structural formula of the sulfonate ester includes \( \text{O=SO}_2-\text{O} \), with the ethyl group connected to the oxygen and the benzene ring connected to the sulfur. **Reaction Description:** - The reaction involves the thiolate anion (formed from the thiol and hydroxide ion) potentially attacking the sulfonate ester. This suggests a nucleophilic substitution reaction, where the sulfur atom can displace the ethyl group from the sulfonate, likely forming an alkyl thioether compound and releasing the sulfonate group. **Diagram Explanation:** - **Arrows:** - A single-headed arrow indicates the progression of the reaction from the reactants (thiol and sulfonate) in the presence of base (OH⁻). It shows the transformation into the corresponding products, not depicted, under the influence of these reactants and conditions. This reaction setup exemplifies typical nucleophilic substitutions in organic chemistry, demonstrating the reactivity of thiolates with suitable leaving groups like sulfonates.
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