H+D2 → HD+D is the exchange of isotopes of hydrogen of atomic mass 1 (H) and 2 (D, deuterium). The following data were obtained for the rate constant k of this reaction: Temperature (K) k (L mol¬1 s-1) 299 1.56 x 104 327 3.77 x 104 346 7.6 x 104 440 106 549 1.07 x 106 745 8.7 x 107 (a) Calculate the activation energy of this reaction. (b) Calculate the factor A in the Arrhenius equation for the temperature dependence of the rate constant.

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
36. The gas-phase reaction
H+D2 → HD+D
is the exchange of isotopes of hydrogen of atomic mass 1 (H) and 2 (D, deuterium). The following
data were obtained for the rate constant k of this reaction:
Temperature (K)
k (L mol¬ s-1)
299
1.56 x 104
327
3.77 x 104
346
7.6 x 101
440
106
549
1.07 x 106
745
8.7 × 107
(a) Calculate the activation energy of this reaction.
(b) Calculate the factor A in the Arrhenius equation for the temperature dependence of the rate
constant.
Transcribed Image Text:36. The gas-phase reaction H+D2 → HD+D is the exchange of isotopes of hydrogen of atomic mass 1 (H) and 2 (D, deuterium). The following data were obtained for the rate constant k of this reaction: Temperature (K) k (L mol¬ s-1) 299 1.56 x 104 327 3.77 x 104 346 7.6 x 101 440 106 549 1.07 x 106 745 8.7 × 107 (a) Calculate the activation energy of this reaction. (b) Calculate the factor A in the Arrhenius equation for the temperature dependence of the rate constant.
Expert Solution
Step 1

Chemistry homework question answer, step 1, image 1

trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 3 steps with 3 images

Blurred answer
Knowledge Booster
Rate Laws
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY