H,C (а) Br F. and Br CH H. CH, H,C H (Ь) and Br F Br F CH, Br CH3 Br H. H- (c) and H,CH F F CH3 H

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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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5.40 Consider the following pairs of structures. Designate cach chirality center as (R) or (S) and identify the relationship bêtween them
by describing them as representing enantiomers, diastereomers, constitutional isomers, or two molecules of the same compound. Use
handheld molecular models to check your answers.
Br CH,
H,C Br
(a)
()
and
and
ĆI
CI
H.
CH
H,C H
CH3
CH3
(b)
and
F
Br
Br
F
CI
CI
-H-
(k)
H-
and
CH,
Br
CH,
Br
H.
-CI
H-
CI
(c)
H,CH
and
F CH3
CH3
CH3
Br
H,C
H.
Br
H-
(1)
-CI
Br-
CH3
and
HH
CI-
Br
(d)
F CH,
H
and
Fu
CH3
Hi
Br
CH,
H,C
CH3
F H
Br
(m)
and
(e)
H,C
and
"F
HC H
Br
H.
CH
Br
and
(n)
and
CH3
CI
(0)
and
CH3
Br
H,CC.
Br
and
Ci
Ci
CI
CI
(h) Cl-
and
-CI
(p)
and
ČI
ČI
CI
Ci CI
Br
and
(q)
Br
Br
C=C=CH
C=Cc=CBr
and
ČI
CI
HIC
Transcribed Image Text:5.40 Consider the following pairs of structures. Designate cach chirality center as (R) or (S) and identify the relationship bêtween them by describing them as representing enantiomers, diastereomers, constitutional isomers, or two molecules of the same compound. Use handheld molecular models to check your answers. Br CH, H,C Br (a) () and and ĆI CI H. CH H,C H CH3 CH3 (b) and F Br Br F CI CI -H- (k) H- and CH, Br CH, Br H. -CI H- CI (c) H,CH and F CH3 CH3 CH3 Br H,C H. Br H- (1) -CI Br- CH3 and HH CI- Br (d) F CH, H and Fu CH3 Hi Br CH, H,C CH3 F H Br (m) and (e) H,C and "F HC H Br H. CH Br and (n) and CH3 CI (0) and CH3 Br H,CC. Br and Ci Ci CI CI (h) Cl- and -CI (p) and ČI ČI CI Ci CI Br and (q) Br Br C=C=CH C=Cc=CBr and ČI CI HIC
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