Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Any help with this would be great! Explanations definitely welcome, thanks in advance for any help:) What is the major product of the reactions?

Transcribed Image Text:The image depicts a chemical reaction involving an alkyne undergoing addition with hydrobromic acid (HBr) in excess. The initial structure is a six-carbon chain with a triple bond between the second and third carbons. The reaction results in the formation of various dibromoalkane products.
**Structures:**
1. **Reactant (Top Structure):**
- A six-carbon alkyne with a triple bond between the second and third carbons.
- Noted: Reaction with HBr (excess).
2. **Products (Labeled a-d):**
a) A six-carbon chain with two bromine atoms added, one each on the second and third carbons.
b) A six-carbon chain where bromine atoms are positioned on the second and fourth carbons, with each bromine on its respective carbon.
c) A six-carbon chain with two bromine atoms added to the third carbon, creating a geminal dibromide.
d) A six-carbon chain with two bromine atoms added. The first bromine is on the fourth carbon, and a bromine atom is placed on what was originally the fifth carbon, forming a vicinal dibromide with a double bond between the second and third carbons.
These structures illustrate the various isomers that can form through the addition of HBr across an alkyne in excess conditions.

Transcribed Image Text:### Reaction and Options:
**Reaction Setup:**
- Starting Material: Benzene ring
- Reagents: DBr (Deuterium Bromide)
- Conditions: -78°C
The goal is to predict the product of the reaction indicated by a question mark.
**Possible Products:**
1. **Structure (a):** A cyclohexene ring with a deuterium (D) atom and a bromine (Br) atom at adjacent carbon positions.
2. **Structure (b):** A cyclohexene ring with a deuterium (D) atom and a bromine (Br) atom at opposite carbon positions.
**Question:**
Which structure is the correct product of the reaction?
- A. (a)
- B. (b)
- C. Not enough information
### Explanation:
The diagram suggests a chemical reaction between benzene and DBr at low temperature, producing one of two possible structural isomers of a brominated, deuterated cyclohexene. The task is to use understanding of isotopic substitution and bromination mechanisms to predict the outcome given the specified conditions.
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