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Half-Reaction E°(V) Half-Reaction E°(V) Ag(s) +0.80 2 H2O(1) + 2e На(3) + 2 Он (аg) — З ОН (aд) Ag" (ag) + e -0.83 AgBr(s) + e Ag(s) + Br (ag) +0.10 HO, (aq) + H,O(1) + 2 e +0.88 AgCI(s) + e Ag(s) + CI (ag) +0.22 H2O2(ag) + 2H*(ag) + 2 e 2 H2O(1) +1.78 Ag(CN)2 (aq) + e Ag(s) + 2 CN (ag) -0.31 Hg+ (ag) + 2e - 2 Hg(1) Hgỷ* (aq) +0.79 Ag2CrO4(s) + 2 e 2 Ag(s) + Cro? (aq) +0.45 2 Hg* (ag) + 2e 2+ +0.92 Agl(s) + e Ag(s) + I(aq) -0.15 Hg²+(aq) + 2e Hg(I) +0.85 Ag(s) + 2 S20 (ag) +0.01 | 1-(s) + 2e 21 (aq) -1.66 | 2 10, (aq) + 12 H*(aq) + 10 e Ag(S203)2 (aq) + e +0.54 Al3* (ag) + 3e Al(s) I2(s) + 6 H,O(1) +1.20 HзAsO,(ag) + 2 н (аg) + 2е НAASO;(ag) + H20(1) +0.56 | к+(аg) + e > K(s) -2.92 Ba" (ag) + 2 e Ba(s) -2.90 LI*(ag) + e ► Li(s) -3.05 Bio*(ag) + 2 H*(ag) + 3 e Bi(s) + H20(1) +0.32 Mg"(ag) + 2 e Mg(s) -2.37 Br2(1) + 2 e 2 Br (aq) +1.07 Mn"(aq) + 2e Mn(s) -1.18 2 BrO; (аq) + 12H (ад) + 10е Br,(1) + 6 H,0(1) +1.52 MnO2(s) + 4 H (aq) + 2e Mn2* (aq) + 2 H2O(I) +1.23 2 CO2(8) + 2H*(aq) + 2 e¯ H2C2O4(aq) -0.49 Mno, (ag) + 8 H*(ag) + Se Mn2* (aq) + 4 H2O(I) +1.51 Ca"(ag) + 2 e Ca(s) -2.87 MnO, (ag) + 2 н,0() + 3е -0.40 HNO2(ag) + H'(ag) + e MnO2(s) + 4 OH (ag) +0.59 Cd2*(aq) + 2 e Cd(s) NO(g) + H20(1) +1.00 Ce*(ag) + e → Ce"(ag) +1.61 | N2(8) + 4 H20(1) + 4 e - 4 OH (ag) + NgH,(ag) -1.16 Cl2(8) + 2e 2 CI (ag) +1.36 N2(8) + 5H*(ag) + 4 e N2H3" (aq) -0.23 Cl,(8) + 2 H,0(I) СI (ag) + 2 ОН (ад) Cl2(8) + 6 H20(1) 2 HCIO(aq) + 2 H'(aq) + 2e +1.63 NO; (ag) + 4 H"(ag) + 3 e NO(8) + 2 H20(1) +0.96 CIO (ag) + H2O(1) + 2e +0.89 | Na"(aq) + e - +1.47 N?*(aq) + 2e Na(s) -2.71 2 CIO3 (ag) + 12 H*(ag) + 10 e Co?*(aq) + 2e Ni(s) -0.28 Co(s) -0.28 O2(8) + 4 H*(ag) + 4e +1.84 0,(8) + 2 H,0(I) + 4e 2 H2O(1) +1.23 Co* (aq) + e Co"(aq) 4 ОН (аg) +0.40 Cr* (ag) + 3 e -0.74 02(8) + 2 H'(aq) + 2e O3(8) + 2 H*(ag) + 2e Cr(s) H2O2(aq) +0.68 • Cr²* (aq) Cr,0,2- (ag) + 14 H*(ag) + 6 e Cr*(ag) + e -0.41 Oz(8) + H20(1) +2.07 2 Cr* (aq) + 7H,O(I) +1.33 Pb?+ (ag) + 2e → Pb(s) -0.13 Cro?- (ag) + 4 H2O(1) + 3e - -0.13 PbO2(s) + HSO4 (ag) + 3 H*(ag) + 2e +1.69 Сг(ОН);(s) + 5 оН (ад) PBSO,(s) + 2 H,0(1) Cu2*(aq) + 2e +0.34 PbSO,(s) + H" (ag) + 2e Pb(s) + HSO, (ag) -0.36 Cu(s) Cu?* (ag) + e Cu"(aq) +0.15 PtCl (ag) + 2 e Pt(s) + 4 CI (aq) +0.73 Cu" (ag) + e Cu(s) +0.52 S(s) + 2 H"(ag) + 2 e H2S(g) +0.14 Cul(s) + e Cu(s) + I (aq) -0.19 H2SO3(ag) + 4 H*(aq) + 4 e S(s) + 3 H20(1) +0.45 2(8) + 2e Fe?* (ag) + 2e » 2F (ag) +2.87 HSO, (ag) + 3 H'(ag) + 2 e H,SO;(aq) + H,O(1) +0.17 ·Fe(s) -0.44 Sn2*(ag) + 2e - Sn(s) -0.14 Fe2" (ag) +0.77 Sn** (aq) + 2e Sn²*(aq) Fe* (ag) + e +0.15 ► Fe(CN) (aq) +0.36 vo,'(ag) + 2H*(aq) + e vo?* (ag) + H,0(1) Fe(CN), (ag) + e +1.00 0.00 Zn2*(ag) + 2e • Zn(s) 2H*(aq) + 2e H2(8) -0.76

Half-Reaction E°(V) Half-Reaction E°(V) Ag(s) +0.80 2 H2O(1) + 2e На(3) + 2 Он (аg) — З ОН (aд) Ag" (ag) + e -0.83 AgBr(s) + e Ag(s) + Br (ag) +0.10 HO, (aq) + H,O(1) + 2 e +0.88 AgCI(s) + e Ag(s) + CI (ag) +0.22 H2O2(ag) + 2H*(ag) + 2 e 2 H2O(1) +1.78 Ag(CN)2 (aq) + e Ag(s) + 2 CN (ag) -0.31 Hg+ (ag) + 2e - 2 Hg(1) Hgỷ* (aq) +0.79 Ag2CrO4(s) + 2 e 2 Ag(s) + Cro? (aq) +0.45 2 Hg* (ag) + 2e 2+ +0.92 Agl(s) + e Ag(s) + I(aq) -0.15 Hg²+(aq) + 2e Hg(I) +0.85 Ag(s) + 2 S20 (ag) +0.01 | 1-(s) + 2e 21 (aq) -1.66 | 2 10, (aq) + 12 H*(aq) + 10 e Ag(S203)2 (aq) + e +0.54 Al3* (ag) + 3e Al(s) I2(s) + 6 H,O(1) +1.20 HзAsO,(ag) + 2 н (аg) + 2е НAASO;(ag) + H20(1) +0.56 | к+(аg) + e > K(s) -2.92 Ba" (ag) + 2 e Ba(s) -2.90 LI*(ag) + e ► Li(s) -3.05 Bio*(ag) + 2 H*(ag) + 3 e Bi(s) + H20(1) +0.32 Mg"(ag) + 2 e Mg(s) -2.37 Br2(1) + 2 e 2 Br (aq) +1.07 Mn"(aq) + 2e Mn(s) -1.18 2 BrO; (аq) + 12H (ад) + 10е Br,(1) + 6 H,0(1) +1.52 MnO2(s) + 4 H (aq) + 2e Mn2* (aq) + 2 H2O(I) +1.23 2 CO2(8) + 2H*(aq) + 2 e¯ H2C2O4(aq) -0.49 Mno, (ag) + 8 H*(ag) + Se Mn2* (aq) + 4 H2O(I) +1.51 Ca"(ag) + 2 e Ca(s) -2.87 MnO, (ag) + 2 н,0() + 3е -0.40 HNO2(ag) + H'(ag) + e MnO2(s) + 4 OH (ag) +0.59 Cd2*(aq) + 2 e Cd(s) NO(g) + H20(1) +1.00 Ce*(ag) + e → Ce"(ag) +1.61 | N2(8) + 4 H20(1) + 4 e - 4 OH (ag) + NgH,(ag) -1.16 Cl2(8) + 2e 2 CI (ag) +1.36 N2(8) + 5H*(ag) + 4 e N2H3" (aq) -0.23 Cl,(8) + 2 H,0(I) СI (ag) + 2 ОН (ад) Cl2(8) + 6 H20(1) 2 HCIO(aq) + 2 H'(aq) + 2e +1.63 NO; (ag) + 4 H"(ag) + 3 e NO(8) + 2 H20(1) +0.96 CIO (ag) + H2O(1) + 2e +0.89 | Na"(aq) + e - +1.47 N?*(aq) + 2e Na(s) -2.71 2 CIO3 (ag) + 12 H*(ag) + 10 e Co?*(aq) + 2e Ni(s) -0.28 Co(s) -0.28 O2(8) + 4 H*(ag) + 4e +1.84 0,(8) + 2 H,0(I) + 4e 2 H2O(1) +1.23 Co* (aq) + e Co"(aq) 4 ОН (аg) +0.40 Cr* (ag) + 3 e -0.74 02(8) + 2 H'(aq) + 2e O3(8) + 2 H*(ag) + 2e Cr(s) H2O2(aq) +0.68 • Cr²* (aq) Cr,0,2- (ag) + 14 H*(ag) + 6 e Cr*(ag) + e -0.41 Oz(8) + H20(1) +2.07 2 Cr* (aq) + 7H,O(I) +1.33 Pb?+ (ag) + 2e → Pb(s) -0.13 Cro?- (ag) + 4 H2O(1) + 3e - -0.13 PbO2(s) + HSO4 (ag) + 3 H*(ag) + 2e +1.69 Сг(ОН);(s) + 5 оН (ад) PBSO,(s) + 2 H,0(1) Cu2*(aq) + 2e +0.34 PbSO,(s) + H" (ag) + 2e Pb(s) + HSO, (ag) -0.36 Cu(s) Cu?* (ag) + e Cu"(aq) +0.15 PtCl (ag) + 2 e Pt(s) + 4 CI (aq) +0.73 Cu" (ag) + e Cu(s) +0.52 S(s) + 2 H"(ag) + 2 e H2S(g) +0.14 Cul(s) + e Cu(s) + I (aq) -0.19 H2SO3(ag) + 4 H*(aq) + 4 e S(s) + 3 H20(1) +0.45 2(8) + 2e Fe?* (ag) + 2e » 2F (ag) +2.87 HSO, (ag) + 3 H'(ag) + 2 e H,SO;(aq) + H,O(1) +0.17 ·Fe(s) -0.44 Sn2*(ag) + 2e - Sn(s) -0.14 Fe2" (ag) +0.77 Sn** (aq) + 2e Sn²*(aq) Fe* (ag) + e +0.15 ► Fe(CN) (aq) +0.36 vo,'(ag) + 2H*(aq) + e vo?* (ag) + H,0(1) Fe(CN), (ag) + e +1.00 0.00 Zn2*(ag) + 2e • Zn(s) 2H*(aq) + 2e H2(8) -0.76

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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H2(g)+F2(g) ⟶ 2H+(aq)+2F−(aq)H2(g)+F2(g) ⟶ 2H+(aq)+2F−(aq)
Express the potential in volts to two decimal places.
 

Part B

Cu2+(aq)+Ca(s) ⟶ Cu(s)+Ca2+(aq)Cu2+(aq)+Ca(s) ⟶ Cu(s)+Ca2+(aq)
Express the potential in volts to two decimal places.
 
 

Part C

3Fe2+(aq) ⟶ Fe(s)+2Fe3+(aq)3Fe2+(aq) ⟶ Fe(s)+2Fe3+(aq)
Express the potential in volts to two decimal places.
 
 

Part D

2ClO3−(aq)+10Br−(aq)+12H+(aq) ⟶ Cl2(g)+5Br2(l)+6H2O(l)2ClO3−(aq)+10Br−(aq)+12H+(aq) ⟶ Cl2(g)+5Br2(l)+6H2O(l)
Express the potential in volts to two decimal places.
Half-Reaction E°(V) Half-Reaction E°(V) Ag(s) +0.80 2 H2O(1) + 2e На(3) + 2 Он (аg) — З ОН (aд) Ag" (ag) + e -0.83 AgBr(s) + e Ag(s) + Br (ag) +0.10 HO, (aq) + H,O(1) + 2 e +0.88 AgCI(s) + e Ag(s) + CI (ag) +0.22 H2O2(ag) + 2H*(ag) + 2 e 2 H2O(1) +1.78 Ag(CN)2 (aq) + e Ag(s) + 2 CN (ag) -0.31 Hg+ (ag) + 2e - 2 Hg(1) Hgỷ* (aq) +0.79 Ag2CrO4(s) + 2 e 2 Ag(s) + Cro? (aq) +0.45 2 Hg* (ag) + 2e 2+ +0.92 Agl(s) + e Ag(s) + I(aq) -0.15 Hg²+(aq) + 2e Hg(I) +0.85 Ag(s) + 2 S20 (ag) +0.01 | 1-(s) + 2e 21 (aq) -1.66 | 2 10, (aq) + 12 H*(aq) + 10 e Ag(S203)2 (aq) + e +0.54 Al3* (ag) + 3e Al(s) I2(s) + 6 H,O(1) +1.20 HзAsO,(ag) + 2 н (аg) + 2е НAASO;(ag) + H20(1) +0.56 | к+(аg) + e > K(s) -2.92 Ba" (ag) + 2 e Ba(s) -2.90 LI*(ag) + e ► Li(s) -3.05 Bio*(ag) + 2 H*(ag) + 3 e Bi(s) + H20(1) +0.32 Mg"(ag) + 2 e Mg(s) -2.37 Br2(1) + 2 e 2 Br (aq) +1.07 Mn"(aq) + 2e Mn(s) -1.18 2 BrO; (аq) + 12H (ад) + 10е Br,(1) + 6 H,0(1) +1.52 MnO2(s) + 4 H (aq) + 2e Mn2* (aq) + 2 H2O(I) +1.23 2 CO2(8) + 2H*(aq) + 2 e¯ H2C2O4(aq) -0.49 Mno, (ag) + 8 H*(ag) + Se Mn2* (aq) + 4 H2O(I) +1.51 Ca"(ag) + 2 e Ca(s) -2.87 MnO, (ag) + 2 н,0() + 3е -0.40 HNO2(ag) + H'(ag) + e MnO2(s) + 4 OH (ag) +0.59 Cd2*(aq) + 2 e Cd(s) NO(g) + H20(1) +1.00 Ce*(ag) + e → Ce"(ag) +1.61 | N2(8) + 4 H20(1) + 4 e - 4 OH (ag) + NgH,(ag) -1.16 Cl2(8) + 2e 2 CI (ag) +1.36 N2(8) + 5H*(ag) + 4 e N2H3" (aq) -0.23 Cl,(8) + 2 H,0(I) СI (ag) + 2 ОН (ад) Cl2(8) + 6 H20(1) 2 HCIO(aq) + 2 H'(aq) + 2e +1.63 NO; (ag) + 4 H"(ag) + 3 e NO(8) + 2 H20(1) +0.96 CIO (ag) + H2O(1) + 2e +0.89 | Na"(aq) + e - +1.47 N?*(aq) + 2e Na(s) -2.71 2 CIO3 (ag) + 12 H*(ag) + 10 e Co?*(aq) + 2e Ni(s) -0.28 Co(s) -0.28 O2(8) + 4 H*(ag) + 4e +1.84 0,(8) + 2 H,0(I) + 4e 2 H2O(1) +1.23 Co* (aq) + e Co"(aq) 4 ОН (аg) +0.40 Cr* (ag) + 3 e -0.74 02(8) + 2 H'(aq) + 2e O3(8) + 2 H*(ag) + 2e Cr(s) H2O2(aq) +0.68 • Cr²* (aq) Cr,0,2- (ag) + 14 H*(ag) + 6 e Cr*(ag) + e -0.41 Oz(8) + H20(1) +2.07 2 Cr* (aq) + 7H,O(I) +1.33 Pb?+ (ag) + 2e → Pb(s) -0.13 Cro?- (ag) + 4 H2O(1) + 3e - -0.13 PbO2(s) + HSO4 (ag) + 3 H*(ag) + 2e +1.69 Сг(ОН);(s) + 5 оН (ад) PBSO,(s) + 2 H,0(1) Cu2*(aq) + 2e +0.34 PbSO,(s) + H" (ag) + 2e Pb(s) + HSO, (ag) -0.36 Cu(s) Cu?* (ag) + e Cu"(aq) +0.15 PtCl (ag) + 2 e Pt(s) + 4 CI (aq) +0.73 Cu" (ag) + e Cu(s) +0.52 S(s) + 2 H"(ag) + 2 e H2S(g) +0.14 Cul(s) + e Cu(s) + I (aq) -0.19 H2SO3(ag) + 4 H*(aq) + 4 e S(s) + 3 H20(1) +0.45 2(8) + 2e Fe?* (ag) + 2e » 2F (ag) +2.87 HSO, (ag) + 3 H'(ag) + 2 e H,SO;(aq) + H,O(1) +0.17 ·Fe(s) -0.44 Sn2*(ag) + 2e - Sn(s) -0.14 Fe2" (ag) +0.77 Sn** (aq) + 2e Sn²*(aq) Fe* (ag) + e +0.15 ► Fe(CN) (aq) +0.36 vo,'(ag) + 2H*(aq) + e vo?* (ag) + H,0(1) Fe(CN), (ag) + e +1.00 0.00 Zn2*(ag) + 2e • Zn(s) 2H*(aq) + 2e H2(8) -0.76
Transcribed Image Text:Half-Reaction E°(V) Half-Reaction E°(V) Ag(s) +0.80 2 H2O(1) + 2e На(3) + 2 Он (аg) — З ОН (aд) Ag" (ag) + e -0.83 AgBr(s) + e Ag(s) + Br (ag) +0.10 HO, (aq) + H,O(1) + 2 e +0.88 AgCI(s) + e Ag(s) + CI (ag) +0.22 H2O2(ag) + 2H*(ag) + 2 e 2 H2O(1) +1.78 Ag(CN)2 (aq) + e Ag(s) + 2 CN (ag) -0.31 Hg+ (ag) + 2e - 2 Hg(1) Hgỷ* (aq) +0.79 Ag2CrO4(s) + 2 e 2 Ag(s) + Cro? (aq) +0.45 2 Hg* (ag) + 2e 2+ +0.92 Agl(s) + e Ag(s) + I(aq) -0.15 Hg²+(aq) + 2e Hg(I) +0.85 Ag(s) + 2 S20 (ag) +0.01 | 1-(s) + 2e 21 (aq) -1.66 | 2 10, (aq) + 12 H*(aq) + 10 e Ag(S203)2 (aq) + e +0.54 Al3* (ag) + 3e Al(s) I2(s) + 6 H,O(1) +1.20 HзAsO,(ag) + 2 н (аg) + 2е НAASO;(ag) + H20(1) +0.56 | к+(аg) + e > K(s) -2.92 Ba" (ag) + 2 e Ba(s) -2.90 LI*(ag) + e ► Li(s) -3.05 Bio*(ag) + 2 H*(ag) + 3 e Bi(s) + H20(1) +0.32 Mg"(ag) + 2 e Mg(s) -2.37 Br2(1) + 2 e 2 Br (aq) +1.07 Mn"(aq) + 2e Mn(s) -1.18 2 BrO; (аq) + 12H (ад) + 10е Br,(1) + 6 H,0(1) +1.52 MnO2(s) + 4 H (aq) + 2e Mn2* (aq) + 2 H2O(I) +1.23 2 CO2(8) + 2H*(aq) + 2 e¯ H2C2O4(aq) -0.49 Mno, (ag) + 8 H*(ag) + Se Mn2* (aq) + 4 H2O(I) +1.51 Ca"(ag) + 2 e Ca(s) -2.87 MnO, (ag) + 2 н,0() + 3е -0.40 HNO2(ag) + H'(ag) + e MnO2(s) + 4 OH (ag) +0.59 Cd2*(aq) + 2 e Cd(s) NO(g) + H20(1) +1.00 Ce*(ag) + e → Ce"(ag) +1.61 | N2(8) + 4 H20(1) + 4 e - 4 OH (ag) + NgH,(ag) -1.16 Cl2(8) + 2e 2 CI (ag) +1.36 N2(8) + 5H*(ag) + 4 e N2H3" (aq) -0.23 Cl,(8) + 2 H,0(I) СI (ag) + 2 ОН (ад) Cl2(8) + 6 H20(1) 2 HCIO(aq) + 2 H'(aq) + 2e +1.63 NO; (ag) + 4 H"(ag) + 3 e NO(8) + 2 H20(1) +0.96 CIO (ag) + H2O(1) + 2e +0.89 | Na"(aq) + e - +1.47 N?*(aq) + 2e Na(s) -2.71 2 CIO3 (ag) + 12 H*(ag) + 10 e Co?*(aq) + 2e Ni(s) -0.28 Co(s) -0.28 O2(8) + 4 H*(ag) + 4e +1.84 0,(8) + 2 H,0(I) + 4e 2 H2O(1) +1.23 Co* (aq) + e Co"(aq) 4 ОН (аg) +0.40 Cr* (ag) + 3 e -0.74 02(8) + 2 H'(aq) + 2e O3(8) + 2 H*(ag) + 2e Cr(s) H2O2(aq) +0.68 • Cr²* (aq) Cr,0,2- (ag) + 14 H*(ag) + 6 e Cr*(ag) + e -0.41 Oz(8) + H20(1) +2.07 2 Cr* (aq) + 7H,O(I) +1.33 Pb?+ (ag) + 2e → Pb(s) -0.13 Cro?- (ag) + 4 H2O(1) + 3e - -0.13 PbO2(s) + HSO4 (ag) + 3 H*(ag) + 2e +1.69 Сг(ОН);(s) + 5 оН (ад) PBSO,(s) + 2 H,0(1) Cu2*(aq) + 2e +0.34 PbSO,(s) + H" (ag) + 2e Pb(s) + HSO, (ag) -0.36 Cu(s) Cu?* (ag) + e Cu"(aq) +0.15 PtCl (ag) + 2 e Pt(s) + 4 CI (aq) +0.73 Cu" (ag) + e Cu(s) +0.52 S(s) + 2 H"(ag) + 2 e H2S(g) +0.14 Cul(s) + e Cu(s) + I (aq) -0.19 H2SO3(ag) + 4 H*(aq) + 4 e S(s) + 3 H20(1) +0.45 2(8) + 2e Fe?* (ag) + 2e » 2F (ag) +2.87 HSO, (ag) + 3 H'(ag) + 2 e H,SO;(aq) + H,O(1) +0.17 ·Fe(s) -0.44 Sn2*(ag) + 2e - Sn(s) -0.14 Fe2" (ag) +0.77 Sn** (aq) + 2e Sn²*(aq) Fe* (ag) + e +0.15 ► Fe(CN) (aq) +0.36 vo,'(ag) + 2H*(aq) + e vo?* (ag) + H,0(1) Fe(CN), (ag) + e +1.00 0.00 Zn2*(ag) + 2e • Zn(s) 2H*(aq) + 2e H2(8) -0.76
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