**Title: Understanding the Reaction Mechanism of Alkyl Chloride with Methanethiolate****Introduction:**In this module, we will explore the detailed mechanism by which an alkyl chloride reacts with methanethiolate ions to form thioethers. This reaction serves as an excellent example of nucleophilic substitution.**Reaction Overview:**1. **Starting Material:** - The reactant is a secondary alkyl chloride, depicted with a chlorine (Cl) atom attached to a carbon in the molecule. 2. **Reagent:** - The nucleophile in this reaction is the methanethiolate ion (\(CH_3S^-\)), often supplied as a salt like sodium methanethiolate. - The reaction occurs in aqueous medium (\(H_2O\)).3. **Products:** - The main product is a thioether, where the chlorine has been substituted by a sulfur group (\(SCH_3\)). - The side product includes another stereoisomer of the thioether with a reversed configuration (\(H_3CS\)). - Chloride ion (\(Cl^-\)) is released as a by-product.**Mechanism Explanation:**- **Nucleophilic Attack:** - The methanethiolate ion (\(CH_3S^-\)), being a strong nucleophile, approaches the carbon atom bonded to the chlorine (Cl) from the opposite side. - This results in a backside attack, which is typical for SN2 reactions, leading to the inversion of configuration at this carbon center.- **Transition State:** - During this process, a transition state is formed where the carbon is partially bonded to both the sulfur and chlorine atoms.- **Displacement:** - The chlorine atom is displaced, resulting in the formation of a new carbon-sulfur (C-S) bond and the cleavage of the carbon-chlorine (C-Cl) bond.- **Products Formation:** - Two stereoisomers of the thioether are produced due to the inversion of configuration at the chiral center. - Chloride ion (\(Cl^-\)) is released into the solution.**Conclusion:**Understanding the mechanism of this reaction provides insight into nucleophilic substitution processes, particularly the SN2 mechanism, which involves a single concerted step with inversion of configuration. This knowledge is fundamental in synthetic organic chemistry for designing reactions that involve halides and

Answered: H3CS.. Draw the full mechanism to show…

H3CS.. Draw the full mechanism to show how this product was made. You must show all the steps and arrows. MXX bo cibers CH3S H₂0 SCH3 Vingylo Avoitong or Teas& Wignon + CL Solidgoolou 100%\book)

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Question

**Title: Understanding the Reaction Mechanism of Alkyl Chloride with Methanethiolate**

**Introduction:**

In this module, we will explore the detailed mechanism by which an alkyl chloride reacts with methanethiolate ions to form thioethers. This reaction serves as an excellent example of nucleophilic substitution.

**Reaction Overview:**

1. **Starting Material:**
- The reactant is a secondary alkyl chloride, depicted with a chlorine (Cl) atom attached to a carbon in the molecule.

2. **Reagent:**
- The nucleophile in this reaction is the methanethiolate ion (\(CH_3S^-\)), often supplied as a salt like sodium methanethiolate.
- The reaction occurs in aqueous medium (\(H_2O\)).

3. **Products:**
- The main product is a thioether, where the chlorine has been substituted by a sulfur group (\(SCH_3\)).
- The side product includes another stereoisomer of the thioether with a reversed configuration (\(H_3CS\)).
- Chloride ion (\(Cl^-\)) is released as a by-product.

**Mechanism Explanation:**

- **Nucleophilic Attack:**
- The methanethiolate ion (\(CH_3S^-\)), being a strong nucleophile, approaches the carbon atom bonded to the chlorine (Cl) from the opposite side.
- This results in a backside attack, which is typical for SN2 reactions, leading to the inversion of configuration at this carbon center.

- **Transition State:**
- During this process, a transition state is formed where the carbon is partially bonded to both the sulfur and chlorine atoms.

- **Displacement:**
- The chlorine atom is displaced, resulting in the formation of a new carbon-sulfur (C-S) bond and the cleavage of the carbon-chlorine (C-Cl) bond.

- **Products Formation:**
- Two stereoisomers of the thioether are produced due to the inversion of configuration at the chiral center.
- Chloride ion (\(Cl^-\)) is released into the solution.

**Conclusion:**

Understanding the mechanism of this reaction provides insight into nucleophilic substitution processes, particularly the SN2 mechanism, which involves a single concerted step with inversion of configuration. This knowledge is fundamental in synthetic organic chemistry for designing reactions that involve halides and

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