Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Provide The major organic products for each reaction
![### Chemical Reactions Involving Alkynes
#### Reaction 1:
- **Reactant:** An alkyne with the following structure: a triple bond followed by a propyl group.
- **Reagents:**
- Water (H₂O)
- Sulfuric acid (H₂SO₄)
- Mercury(II) sulfate (HgSO₄)
This reaction typically results in the addition of water (hydration) across the triple bond, converting the alkyne into a ketone through an enol intermediate.
#### Reaction 2:
- **Reactants:**
1. An alkyne with the structure `CH₃—C≡C—CH₃`
2. Hydrogen gas (H₂)
- **Catalyst:** Lindlar catalyst
The alkyne undergoes partial hydrogenation in the presence of Lindlar's catalyst to form an alkene (designated as compound A).
- **Subsequent Reaction with Compound A:**
- **Reagents:**
- Methanol (CH₃OH)
- Sulfuric acid (H₂SO₄)
This reaction involves further transformation to produce compound B, typically through an etherification or hydration process.
These reactions illustrate the conversion of alkynes to more functionalized organic compounds, demonstrating important synthetic transformations in organic chemistry.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fd9236b64-b4cd-48d9-84e5-ba64ef39dc54%2F5d802c00-be1b-40ac-991d-97a19fe9448f%2F0xl83ds_processed.jpeg&w=3840&q=75)
Transcribed Image Text:### Chemical Reactions Involving Alkynes
#### Reaction 1:
- **Reactant:** An alkyne with the following structure: a triple bond followed by a propyl group.
- **Reagents:**
- Water (H₂O)
- Sulfuric acid (H₂SO₄)
- Mercury(II) sulfate (HgSO₄)
This reaction typically results in the addition of water (hydration) across the triple bond, converting the alkyne into a ketone through an enol intermediate.
#### Reaction 2:
- **Reactants:**
1. An alkyne with the structure `CH₃—C≡C—CH₃`
2. Hydrogen gas (H₂)
- **Catalyst:** Lindlar catalyst
The alkyne undergoes partial hydrogenation in the presence of Lindlar's catalyst to form an alkene (designated as compound A).
- **Subsequent Reaction with Compound A:**
- **Reagents:**
- Methanol (CH₃OH)
- Sulfuric acid (H₂SO₄)
This reaction involves further transformation to produce compound B, typically through an etherification or hydration process.
These reactions illustrate the conversion of alkynes to more functionalized organic compounds, demonstrating important synthetic transformations in organic chemistry.
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