H1 N1 Cal Residue 1 01 C1 N2 H2 Ca2 02 Residue 2 C2 | Ca2 adopts the (S)-configuration. The partial double-bond character of the peptide bond restricts rotation around the bond connecting C1 to N2. Residue 1 is D-alanine. The peptide bond connecting residue 1 to residue 2 is in the CIS conformation, because atoms 01 and Ca2 lie on the SAME side of the peptide bond connecting atoms C1 and N2. The partial double-bond character of the peptide bond requires that atoms Ca1, C1, 01, N2, H2 and Ca2 must lie in the same plane.

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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For the dipeptide drawn below, please select all of the statements that are
completely correct:
H1
N1
Cal
Residue 1
01
C1
N2
H2
Ca2
02
Residue 2
C2
Ca2 adopts the (S)-configuration.
The partial double-bond character of the peptide bond restricts rotation around
the bond connecting C1 to N2.
Residue 1 is D-alanine.
The peptide bond connecting residue 1 to residue 2 is in the CIS conformation,
because atoms 01 and Ca2 lie on the SAME side of the peptide bond
connecting atoms C1 and N2.
The partial double-bond character of the peptide bond requires that atoms Ca1,
C1, 01, N2, H2 and Ca2 must lie in the same plane.
Transcribed Image Text:For the dipeptide drawn below, please select all of the statements that are completely correct: H1 N1 Cal Residue 1 01 C1 N2 H2 Ca2 02 Residue 2 C2 Ca2 adopts the (S)-configuration. The partial double-bond character of the peptide bond restricts rotation around the bond connecting C1 to N2. Residue 1 is D-alanine. The peptide bond connecting residue 1 to residue 2 is in the CIS conformation, because atoms 01 and Ca2 lie on the SAME side of the peptide bond connecting atoms C1 and N2. The partial double-bond character of the peptide bond requires that atoms Ca1, C1, 01, N2, H2 and Ca2 must lie in the same plane.
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