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-오 H. SOCI, base [assume SN2] H H. OH H-CI Me. Me Me

-오 H. SOCI, base [assume SN2] H H. OH H-CI Me. Me Me

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Draw the main product you expect from each reaction below. Pay attention to the stereochemistry.
The image shows a chemical reaction scheme involving the transformation of a cyclohexanol derivative. **Reaction Details**: 1. **Reactant**: A cyclohexanol derivative featuring two methyl groups on the same carbon as the hydroxyl group (OH) and one methyl group on the adjacent carbon. The structure is a cyclohexane ring with the following substituents: - Two methyl groups (Me) on the carbon with the hydroxyl group. - An additional methyl group on the next carbon in the ring. 2. **Reagents**: - The reaction uses thionyl chloride (SOCl₂) and a base. - The reaction assumes an SN2 reaction mechanism. 3. **Product**: - The product is another cyclohexanol derivative with two hydrogen atoms on different carbons and the hydroxyl group transferred. **Side Product**: - HCl is released during the reaction as a byproduct. **Mechanism Overview**: - The SN2 mechanism indicates a bimolecular nucleophilic substitution where the nucleophile attacks the substrate, leading to a transition state and inversion of configuration. This reaction typically converts alcohols to alkyl chlorides, and in this context, it involves a cyclohexanol to a different structural isomer via interaction with thionyl chloride in the presence of a base.
Transcribed Image Text:The image shows a chemical reaction scheme involving the transformation of a cyclohexanol derivative. **Reaction Details**: 1. **Reactant**: A cyclohexanol derivative featuring two methyl groups on the same carbon as the hydroxyl group (OH) and one methyl group on the adjacent carbon. The structure is a cyclohexane ring with the following substituents: - Two methyl groups (Me) on the carbon with the hydroxyl group. - An additional methyl group on the next carbon in the ring. 2. **Reagents**: - The reaction uses thionyl chloride (SOCl₂) and a base. - The reaction assumes an SN2 reaction mechanism. 3. **Product**: - The product is another cyclohexanol derivative with two hydrogen atoms on different carbons and the hydroxyl group transferred. **Side Product**: - HCl is released during the reaction as a byproduct. **Mechanism Overview**: - The SN2 mechanism indicates a bimolecular nucleophilic substitution where the nucleophile attacks the substrate, leading to a transition state and inversion of configuration. This reaction typically converts alcohols to alkyl chlorides, and in this context, it involves a cyclohexanol to a different structural isomer via interaction with thionyl chloride in the presence of a base.
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