h² (3n2/3 2m 87 E,(0) = (42.23) e TABLE 42.1 Calculated Values of the Fermi Energy for Metals at 300 K Based on the Free-Electron Theory Metal Electron Concentration (m-3) Fermi Energy (eV) Li 4.70 X 1028 4.72 Na 2.65 X 1028 3.23 1.40 X 1028 8.46 × 1028 K 2.12 Cu 7.05 Ag Au 5.85 X 1028 5.48 5.90 X 1028 5.53

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(a) State what the Fermi energy depends on according to the free-electron theory of metals and how the Fermi energy depends on that quantity. (b) Show that Equation 42.23 can be expressed as EF = (3.65 x 10-19)ne 2/3, where EF is in electron volts when ne is in electrons per cubic meter. (c) According to Table 42.1, by what factor does the free-electron concentration in copper exceed that in potassium? (d) Which of these metals has the larger Fermi energy? (e) By what factor is the Fermi energy larger? (f) Explain whether this behavior is predicted by Equation 42.23.

h² (3n2/3
2m 87
E,(0) =
(42.23)
e
Transcribed Image Text:h² (3n2/3 2m 87 E,(0) = (42.23) e
TABLE 42.1 Calculated Values of the Fermi Energy for Metals
at 300 K Based on the Free-Electron Theory
Metal
Electron Concentration (m-3)
Fermi Energy (eV)
Li
4.70 X 1028
4.72
Na
2.65 X 1028
3.23
1.40 X 1028
8.46 × 1028
K
2.12
Cu
7.05
Ag
Au
5.85 X 1028
5.48
5.90 X 1028
5.53
Transcribed Image Text:TABLE 42.1 Calculated Values of the Fermi Energy for Metals at 300 K Based on the Free-Electron Theory Metal Electron Concentration (m-3) Fermi Energy (eV) Li 4.70 X 1028 4.72 Na 2.65 X 1028 3.23 1.40 X 1028 8.46 × 1028 K 2.12 Cu 7.05 Ag Au 5.85 X 1028 5.48 5.90 X 1028 5.53
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