Gold can be determined in solutions containing high concentrations of diverse ions by ICP-AES. Aliquots of 50.0 mL of the sample solution were transferred to each of four 100.0 mL volumetric flasks. A solution was prepared containing 10.0 mg/L Au in 20% H₂SO4 and quantities of this solution were added to the sample solutions to give 0, 2.5, 5, and 10 mg/L added Au in each of the flasks. The solutions were made up to a total volume of 100.0 mL, mixed, and analysed by ICP-AES. The resulting data are presented in the following table. Added Au, mg/L Emission Intensity Count 0.0 12,568 2.5 19,324 5.0 26,622 10.0 40,021 Calculate the concentration of gold in the original sample.

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Note: The Emission Intensity of the original solution is not given since the calibration method is standard addition.

Gold can be determined in solutions containing high concentrations of diverse ions by ICP-AES. Aliquots of 50.0
mL of the sample solution were transferred to each of four 100.0 mL volumetric flasks. A solution was prepared
containing 10.0 mg/L Au in 20% H₂SO4 and quantities of this solution were added to the sample solutions to give
0, 2.5, 5, and 10 mg/L added Au in each of the flasks. The solutions were made up to a total volume of 100.0
mL, mixed, and analysed by ICP-AES. The resulting data are presented in the following table.
Added Au, mg/L
Emission Intensity Count
0.0
12,568
2.5
19,324
5.0
26,622
10.0
40,021
Calculate the concentration of gold in the original sample.
Transcribed Image Text:Gold can be determined in solutions containing high concentrations of diverse ions by ICP-AES. Aliquots of 50.0 mL of the sample solution were transferred to each of four 100.0 mL volumetric flasks. A solution was prepared containing 10.0 mg/L Au in 20% H₂SO4 and quantities of this solution were added to the sample solutions to give 0, 2.5, 5, and 10 mg/L added Au in each of the flasks. The solutions were made up to a total volume of 100.0 mL, mixed, and analysed by ICP-AES. The resulting data are presented in the following table. Added Au, mg/L Emission Intensity Count 0.0 12,568 2.5 19,324 5.0 26,622 10.0 40,021 Calculate the concentration of gold in the original sample.
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