Given the van der Waals constants for ethane gas as a = 5.562L2bar/mol2, b = 0.06380L/mol, for 10.0 mol of ethane at 300 K and under 30 bar i.Calculate the second virial coefficient B at this temperature. ii.What does this imply about the nature of the interactions between the molecules at this temperature?
Given the van der Waals constants for ethane gas as a = 5.562L2bar/mol2, b = 0.06380L/mol, for 10.0 mol of ethane at 300 K and under 30 bar i.Calculate the second virial coefficient B at this temperature. ii.What does this imply about the nature of the interactions between the molecules at this temperature?
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Given the van der Waals constants for ethane gas as a = 5.562L2bar/mol2, b = 0.06380L/mol, for 10.0 mol of ethane at 300 K and under 30 bar
i.Calculate
the second virial coefficient B at this temperature.
ii.What does this imply about the nature of the interactions between the
molecules at this temperature?
iii.Calculate the compression factor (Z)
from the first two terms of the virial
equation of state
.
iv.
Estimate
the molar
volume from Z.
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