Given that at 25.0 °C K for HCN is 4.9 x 10-10 and Kb for NH3 is 1.8 x 10-5. calculate Kb for CN and • • K, for NH₂¹. Enter the K, value for CN followed by the K₂ value for NH4+, separated by a comma, using two significant figures. ▸ View Available Hint(s)

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
icon
Concept explainers
Question
+ Acid-Base Properties of Salt Solutions
Salt is an ionic compound that is produced when a cation and an anion
from an acid-base reaction combine, and solutions of salts can be neutral,
acidic, or basic, depending on the acid-base properties of the constituent
cations and anions.
Since strong acids and bases completely ionize in solution, the reaction
essentially runs to completion forming the salt. Therefore, salts formed by
reaction of a strong acid with a strong base are neutral. NaCl formed by
the neutralization of NaOH and HCl is a neutral salt.
Salts formed by reaction of a strong acid with a weak base are acidic, and
salts formed by reaction of a weak acid with a strong base are basic. This
is due to the equilibrium the conjugate has with its acid or base. For
example, sodium bicarbonate NaHCO3 contains the conjugate of the
weak acid H₂CO3. The conjugate will reform the acid through the
equilibrium
HCO3(aq) + H₂O(aq) = H₂CO3(aq) + HO (aq)
and, thus, acts as a weak base. A solution of NaHCO3 yields a basic
solution.
If a salt is derived from a weak acid and a weak base, the pH of the
solution depends on the relative acid strength (K₂) of the cation and base
strength (Kb) of the anion. If Ka > Kb. the solution of the salt is acidic.
If K₂ < Kb. it is basic. If K₂ Kb. it is neutral.
Part A
Given that at 25.0 °C
.
•
Ka for HCN is 4.9 x 10 10 an
and
Kb for NH3 is 1.8 x 10-5.
calculate
• Kh for CN and
Ka for NH4+
Enter the K, value for CN followed by the K₂ value for NH4+, separated by a comma, using two significant figures.
▶ View Available Hint(s)
|VG ΑΣΦ 6
Submit
Previous Answers
?
X Incorrect; Try Again; 5 attempts remaining
Transcribed Image Text:+ Acid-Base Properties of Salt Solutions Salt is an ionic compound that is produced when a cation and an anion from an acid-base reaction combine, and solutions of salts can be neutral, acidic, or basic, depending on the acid-base properties of the constituent cations and anions. Since strong acids and bases completely ionize in solution, the reaction essentially runs to completion forming the salt. Therefore, salts formed by reaction of a strong acid with a strong base are neutral. NaCl formed by the neutralization of NaOH and HCl is a neutral salt. Salts formed by reaction of a strong acid with a weak base are acidic, and salts formed by reaction of a weak acid with a strong base are basic. This is due to the equilibrium the conjugate has with its acid or base. For example, sodium bicarbonate NaHCO3 contains the conjugate of the weak acid H₂CO3. The conjugate will reform the acid through the equilibrium HCO3(aq) + H₂O(aq) = H₂CO3(aq) + HO (aq) and, thus, acts as a weak base. A solution of NaHCO3 yields a basic solution. If a salt is derived from a weak acid and a weak base, the pH of the solution depends on the relative acid strength (K₂) of the cation and base strength (Kb) of the anion. If Ka > Kb. the solution of the salt is acidic. If K₂ < Kb. it is basic. If K₂ Kb. it is neutral. Part A Given that at 25.0 °C . • Ka for HCN is 4.9 x 10 10 an and Kb for NH3 is 1.8 x 10-5. calculate • Kh for CN and Ka for NH4+ Enter the K, value for CN followed by the K₂ value for NH4+, separated by a comma, using two significant figures. ▶ View Available Hint(s) |VG ΑΣΦ 6 Submit Previous Answers ? X Incorrect; Try Again; 5 attempts remaining
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 2 steps

Blurred answer
Knowledge Booster
Thermochemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY