Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Give the structure of the starting reactant for the reaction sequence shown below:

Transcribed Image Text:The image depicts a chemical reaction sequence consisting of three steps leading to the formation of an aldehyde. The process is as follows:
1. **BH₃·THF**: The first step involves the use of borane in tetrahydrofuran (THF). BH₃·THF is commonly used as a reagent in hydroboration reactions, which typically add a boron atom across a carbon-carbon double bond, resulting in the formation of an organoborane intermediate.
2. **H₂O₂, OH⁻**: The second step includes the use of hydrogen peroxide (H₂O₂) in the presence of a hydroxide ion (OH⁻). This step is indicative of an oxidation reaction, where the organoborane intermediate is oxidized, resulting in the conversion to an alcohol.
3. **PCC**: The third step utilizes Pyridinium chlorochromate (PCC), a reagent used to oxidize primary alcohols to aldehydes without further oxidation to carboxylic acids.
**Chemical Structure Described**:
The final product is an aldehyde with a benzene ring attached to a two-carbon chain ending in a formyl group (−CHO). This structure is indicative of phenylacetaldehyde, a compound with a benzene ring and an aldehyde group separated by a two-carbon chain.
This reaction demonstrates the conversion of an alkene to an aldehyde via hydroboration-oxidation followed by selective oxidation using PCC.
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