Answered: Give the major organic product(s) of…

Give the major organic product(s) of each of the following reactions. If none is predicted, write "N.R." CH,CCI AICI, CH30- O p-acetoanisole O m-acetoanisole O o- and p-acetoanisole O o-acetoanisole

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter16: Aldehydes And Ketones

Section: Chapter Questions

Problem 16.42P: When cis-2-decalone is dissolved in ether containing a trace of HCl, an equilibrium is established...

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Give the major organic product(s) of each of the following reactions. If none is predicted, write "N.R."
CH;0
CH;CI
AIC,
O p-acetoanisole
O m-acetoanisole
O o- and p-acetoanisole
O o-acetoanisole

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When cis-2-decalone is dissolved in ether containing a trace of HCl, an equilibrium is established with trans-2-decalone. The latter ketone predominates in the equilibrium mixture. Propose a mechanism for this isomerization and account for the fact that the trans isomer predominates at equilibrium.
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