Gaseous phosphorus pentachloride decomposes according to the reaction PCIs(g) PCl3(g)+Cl2(g) a. The equilibrium system was analyzed at a particular temperature, and the concentrations of the substances present were determined to be [PCIs] =1.1x10-²M, [PC13]=0.325M, and [Cl₂]=3.9x10-3M. Calculate the value of K for the reaction. b. Using your value of K, determine the concentration of [Cl2] present when [PCIs] =5.0× 10-³M and [PC13] -0.225M.

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Topic 14 HW
1. Write the equilibrium expression for each of the following reactions.
a. 203(g) 302(g)
b. CH4(g)+2O2(g)=CO2(g) +2H2O(g)
c. P4(s) +502(g)=P4010(s)
*NH CHECO0+MM
d. CO2(g)+2NaOH(s) Na2CO3(s) +H₂O(g)
2. Gaseous phosphorus pentachloride decomposes according to the reaction
Crack
Name:
PCIs(g) PCl3(g)+Cl2(g)
a. The equilibrium system was analyzed at a particular temperature, and the
conce rations of the substances present were determined to be [PCIs] =1.1×10-²M,
[PC13]=0.325M, and [Cl2] =3.9x10-³M. Calculate the value of K for the reaction.
b. Using your value of K, determine the concentration of [Cl2] present when
[PCIs] =5.0× 10-³M and [PC13] -0.225M.
3. Suppose the reaction system has already reached equilibrium.
Energy + 2NO(g) + O2(g) 2NO2(g)
Predict the effect of each of the following changes on the position of the equilibrium. Tell
whether the equilibrium will shift to the right, will shift to the left, or will not be affected.
a. Additional oxygen is injected into the system.
b. NO2 is removed from the reaction vessel.
c. 1.0 mole of helium is injected into the system.
d. The temperature is decreased and what is also special about this adjustment.
Transcribed Image Text:Topic 14 HW 1. Write the equilibrium expression for each of the following reactions. a. 203(g) 302(g) b. CH4(g)+2O2(g)=CO2(g) +2H2O(g) c. P4(s) +502(g)=P4010(s) *NH CHECO0+MM d. CO2(g)+2NaOH(s) Na2CO3(s) +H₂O(g) 2. Gaseous phosphorus pentachloride decomposes according to the reaction Crack Name: PCIs(g) PCl3(g)+Cl2(g) a. The equilibrium system was analyzed at a particular temperature, and the conce rations of the substances present were determined to be [PCIs] =1.1×10-²M, [PC13]=0.325M, and [Cl2] =3.9x10-³M. Calculate the value of K for the reaction. b. Using your value of K, determine the concentration of [Cl2] present when [PCIs] =5.0× 10-³M and [PC13] -0.225M. 3. Suppose the reaction system has already reached equilibrium. Energy + 2NO(g) + O2(g) 2NO2(g) Predict the effect of each of the following changes on the position of the equilibrium. Tell whether the equilibrium will shift to the right, will shift to the left, or will not be affected. a. Additional oxygen is injected into the system. b. NO2 is removed from the reaction vessel. c. 1.0 mole of helium is injected into the system. d. The temperature is decreased and what is also special about this adjustment.
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