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g. None are true B). Which is not true of acid halides and anhydrides (put all that apply)? a. Acid halides can be formed from aldehydes and ketones using thionyl chloride b. Prefer to undergo acyl addition c. Prefer to undergo acyl substitution d. Generally prefers to form alcohols with organometallic reactions unless contro e. Used in the Claisen reaction f. Used in the iodoform (a-halo carbonyl) reactions g. All are true h. None are true

g. None are true B). Which is not true of acid halides and anhydrides (put all that apply)? a. Acid halides can be formed from aldehydes and ketones using thionyl chloride b. Prefer to undergo acyl addition c. Prefer to undergo acyl substitution d. Generally prefers to form alcohols with organometallic reactions unless contro e. Used in the Claisen reaction f. Used in the iodoform (a-halo carbonyl) reactions g. All are true h. None are true

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Please answer each part A B and C
(A). Which is NOT true of esters and amides (put all that apply)? a. Alpha hydrogens are typieally less aeidie than aldehydes and ketønes alpha hydrogens b. Backbones generally have restricted rotation by resonance into an sp state c. Both can be converted to carboxylic acids with hydrolysis d. Esters create B-keto esters with enolate chemistry e. Contain good leaving groups f. All are true g. None are true B. Which is not true of acid halides and anhydrides (put all that apply)? a. Acid halides can be formed from aldehydes and ketones using thionyl chloride (SOCI b. Prefer to undergo acyl addition c. Prefer to undergo acyl substitution d. Generally prefers to form alcohols with organometallic reactions unless controlled e. Used in the Claisen reaction f. Used in the iodoform (a-halo carbonyl) reactions g. All are true h. None are true Which is NOT true of a,ß-unsaturated carbonyl systems (put all that apply)? a. Contains a conjugated system b. Is less stable than a similar structured ketone c. Acyl substitution is preferred with non-organometallic reagents d. Aldol reactions are often called Michael reactions/products e. Acyl addition is preferred with magnesium and lithium organometallic reagents f. 1,4 addition is preferred with copper organometallic reagents g. All are true h. None are true
Transcribed Image Text:(A). Which is NOT true of esters and amides (put all that apply)? a. Alpha hydrogens are typieally less aeidie than aldehydes and ketønes alpha hydrogens b. Backbones generally have restricted rotation by resonance into an sp state c. Both can be converted to carboxylic acids with hydrolysis d. Esters create B-keto esters with enolate chemistry e. Contain good leaving groups f. All are true g. None are true B. Which is not true of acid halides and anhydrides (put all that apply)? a. Acid halides can be formed from aldehydes and ketones using thionyl chloride (SOCI b. Prefer to undergo acyl addition c. Prefer to undergo acyl substitution d. Generally prefers to form alcohols with organometallic reactions unless controlled e. Used in the Claisen reaction f. Used in the iodoform (a-halo carbonyl) reactions g. All are true h. None are true Which is NOT true of a,ß-unsaturated carbonyl systems (put all that apply)? a. Contains a conjugated system b. Is less stable than a similar structured ketone c. Acyl substitution is preferred with non-organometallic reagents d. Aldol reactions are often called Michael reactions/products e. Acyl addition is preferred with magnesium and lithium organometallic reagents f. 1,4 addition is preferred with copper organometallic reagents g. All are true h. None are true
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