From the picture and description can you is that a correct mechanism . can you draw the mechanism ? Phosphate Ester (Minor Product): In the mechanism, a nucleophilic attack by the phosphate ion (�2��4−H2PO4−) substitutes the hydroxyl group in the protonated cyclohexanol. This is a minor product due to steric hindrance. The phosphate group is relatively large and bulky, making the substitution reaction less favored. The size of the substituent may lead to a slower reaction rate and decreased likelihood of successful substitution. Ether (Minor Product): In the mechanism, substitution involves another cyclohexanol molecule attacking the hydroxyl group in the protonated cyclohexanol. Steric hindrance and the availability of a more favorable elimination pathway (dehydration) contribute to the ether being a minor product. The proximity of two cyclohexanol molecules for substitution is hindered by steric factors, making elimination more favorable.
From the picture and description can you is that a correct mechanism . can you draw the mechanism ? Phosphate Ester (Minor Product): In the mechanism, a nucleophilic attack by the phosphate ion (�2��4−H2PO4−) substitutes the hydroxyl group in the protonated cyclohexanol. This is a minor product due to steric hindrance. The phosphate group is relatively large and bulky, making the substitution reaction less favored. The size of the substituent may lead to a slower reaction rate and decreased likelihood of successful substitution. Ether (Minor Product): In the mechanism, substitution involves another cyclohexanol molecule attacking the hydroxyl group in the protonated cyclohexanol. Steric hindrance and the availability of a more favorable elimination pathway (dehydration) contribute to the ether being a minor product. The proximity of two cyclohexanol molecules for substitution is hindered by steric factors, making elimination more favorable.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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From the picture and description can you is that a correct mechanism . can you draw the mechanism ?
-
Phosphate Ester (Minor Product):
- In the mechanism, a nucleophilic attack by the phosphate ion (�2��4−H2PO4−) substitutes the hydroxyl group in the protonated cyclohexanol.
- This is a minor product due to steric hindrance. The phosphate group is relatively large and bulky, making the substitution reaction less favored. The size of the substituent may lead to a slower reaction rate and decreased likelihood of successful substitution.
-
Ether (Minor Product):
- In the mechanism, substitution involves another cyclohexanol molecule attacking the hydroxyl group in the protonated cyclohexanol.
- Steric hindrance and the availability of a more favorable elimination pathway (dehydration) contribute to the ether being a minor product. The proximity of two cyclohexanol molecules for substitution is hindered by steric factors, making elimination more favorable.
![1. Phosphate Ester Formation:
C6H11OH2+ + H2PO4-
2. Ether Formation:
Substitution
C6H11OH2+ + C6H110H
C6H11OP (O)(OH)2 + H3O+
Substitution
C6H11OC6H11 + H3O+](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F9b0e7686-0c0d-4eba-ac81-54e736b47f2f%2F4da9d4fd-9ce0-449a-a524-d24a3f0f3505%2F2qvwe3b_processed.png&w=3840&q=75)
Transcribed Image Text:1. Phosphate Ester Formation:
C6H11OH2+ + H2PO4-
2. Ether Formation:
Substitution
C6H11OH2+ + C6H110H
C6H11OP (O)(OH)2 + H3O+
Substitution
C6H11OC6H11 + H3O+
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