fraction of the CCI4 is converted into C and Cl2? (b) What are the partial pressures of CC14 and Cl2 at equilibrium? are the partial pressures of CCI4 and Ci [15,90] The reaction PCI3(8) + Cl2(8) = PCI5(8) has Kp= 0.0870 at 300 °C. A flask is charged with 0.50 atm PCI3, 0.50 atm Cl2, and 0.20 atm PCI5 at this temperaturte. (a) Use the reaction quotient to determine the direction the reaction must proceed to reach equilibrium. (b) Calcu- late the equilibrium partial pressures of the gases. (c) What Kp offect will increasing the volume of the system hav What mole fraction of Cl, in the equilibrium mixture? (d) The reaction is exothermic. What effect will increasing the tem- perature of the system have on the mole fraction of Cl, in the equilibrium mixture? 15.91] An equilibrium mixture of H2, 12, and HI at 458 °C con. tains 0.112 mol H2, 0.112 mol I2, and 0.775 mol HI in a 5.00-L vessel. What are the equilibrium partial pressures when equilibrium is reestablished following the addition of 0.200 mol of HI? .92] Consider the hypothetical reaction A(g) + 2 B(g) = 2 C(g), for which K, 1.00-L reaction vessel is loaded with 1.00 mol of com- pound C, which is allowed to reach equilibrium. Let the variable x represent the number of mol/L of compound 0.25 at a certain temperature. A A present at equilibrium. (a) In terms of x, what are the equilibrium concentrations of compounds B and C? (b) What limits must be placed on the value of x so that all concentration the equilib-

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Question 15.90 part A and C

fraction of the CCI4 is converted into C and Cl2? (b) What
are the partial pressures of CC14 and Cl2 at equilibrium?
are the partial pressures of CCI4 and Ci
[15,90] The reaction PCI3(8) + Cl2(8) = PCI5(8) has Kp=
0.0870 at 300 °C. A flask is charged with 0.50 atm
PCI3, 0.50 atm Cl2, and 0.20 atm PCI5 at this temperaturte.
(a) Use the reaction quotient to determine the direction
the reaction must proceed to reach equilibrium. (b) Calcu-
late the equilibrium partial pressures of the gases. (c) What
Kp
offect will increasing the volume of the system hav What
mole fraction of Cl, in the equilibrium mixture? (d) The
reaction is exothermic. What effect will increasing the tem-
perature of the system have on the mole fraction of Cl, in
the equilibrium mixture?
15.91] An equilibrium mixture of H2, 12, and HI at 458 °C con.
tains 0.112 mol H2, 0.112 mol I2, and 0.775 mol HI in a
5.00-L vessel. What are the equilibrium partial pressures
when equilibrium is reestablished following the addition
of 0.200 mol of HI?
.92] Consider the hypothetical reaction A(g) + 2 B(g) =
2 C(g), for which K,
1.00-L reaction vessel is loaded with 1.00 mol of com-
pound C, which is allowed to reach equilibrium. Let the
variable x represent the number of mol/L of compound
0.25 at a certain temperature. A
A present at equilibrium. (a) In terms of x, what are the
equilibrium concentrations of compounds B and C?
(b) What limits must be placed on the value of x so that
all concentration
the equilib-
Transcribed Image Text:fraction of the CCI4 is converted into C and Cl2? (b) What are the partial pressures of CC14 and Cl2 at equilibrium? are the partial pressures of CCI4 and Ci [15,90] The reaction PCI3(8) + Cl2(8) = PCI5(8) has Kp= 0.0870 at 300 °C. A flask is charged with 0.50 atm PCI3, 0.50 atm Cl2, and 0.20 atm PCI5 at this temperaturte. (a) Use the reaction quotient to determine the direction the reaction must proceed to reach equilibrium. (b) Calcu- late the equilibrium partial pressures of the gases. (c) What Kp offect will increasing the volume of the system hav What mole fraction of Cl, in the equilibrium mixture? (d) The reaction is exothermic. What effect will increasing the tem- perature of the system have on the mole fraction of Cl, in the equilibrium mixture? 15.91] An equilibrium mixture of H2, 12, and HI at 458 °C con. tains 0.112 mol H2, 0.112 mol I2, and 0.775 mol HI in a 5.00-L vessel. What are the equilibrium partial pressures when equilibrium is reestablished following the addition of 0.200 mol of HI? .92] Consider the hypothetical reaction A(g) + 2 B(g) = 2 C(g), for which K, 1.00-L reaction vessel is loaded with 1.00 mol of com- pound C, which is allowed to reach equilibrium. Let the variable x represent the number of mol/L of compound 0.25 at a certain temperature. A A present at equilibrium. (a) In terms of x, what are the equilibrium concentrations of compounds B and C? (b) What limits must be placed on the value of x so that all concentration the equilib-
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