Four solutions of an acid dissolved in water are sketched below, as if under a microscope so powerful individual atoms could solution is shown in each sketch. Rank the solutions by the strength of the dissolved acid. That is, select 1 under the solution of the strongest acid, 2 under the solution of the next strongest acid, and so on. Note: seen. The same volume of = H₂O

Four solutions of an acid dissolved in water are sketched below, as if under a microscope so powerful individual atoms could solution is shown in each sketch. Rank the solutions by the strength of the dissolved acid. That is, select 1 under the solution of the strongest acid, 2 under the solution of the next strongest acid, and so on. Note: seen. The same volume of = H₂O

Chemistry: Principles and Reactions

8th Edition

ISBN:9781305079373

Author:William L. Masterton, Cecile N. Hurley

Publisher:William L. Masterton, Cecile N. Hurley

Chapter14: Equilibria In Acid-base Solutions

Section: Chapter Questions

Problem 62QAP: Use the same symbols as in Question 61 ( = anion, =OH) for the box below. (a) Fill in a similar box...

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For oxyacids, how does acid strength depend on a. the strength of the bond to the acidic hydrogen atom? b. the electronegativity of the element bonded to the oxygen atom that bears the acidic hydrogen? c. the number of oxygen atoms? How does the strength of a conjugate base depend on these factors? What type of solution forms when a nonmetal oxide dissolves in water? Give an example of such an oxide. What type of solution forms when a metal oxide dissolves in water? Give an example of such an oxide.
Strong Acids, Weak Acids, and pH Two 0.10-mol samples of the hypothetical monoprotic acids HA(aq) and HB(aq) are used to prepare 1.0-L stock solutions of each acid. a Write the chemical reactions for these acids in water. What are the concentrations of the two acid solutions? b One of these acids is a strong acid, and one is weak. What could you measure that would tell you which acid was strong and which was weak? c Say that the HA(aq) solution has a pH of 3.7. Is this the stronger of the two acids? How did you arrive at your answer? d What is the concentration of A(aq) in the HA solution described in part c? e If HB(aq) is a strong acid, what is the hydronium-ion concentration? f In the solution of HB(aq), which of the following would you expect to be in the greatest concentration: H3O+(aq), B(aq), HB(aq), or OH(aq)? How did you decide? g In the solution of HA(aq), which of the following would you expect to be in the greatest concentration: H3O+(aq), A+(aq), HA(aq), or OH(aq)? How did you decide? h Say you add 1.0 L of pure water to a solution of HB. Would this water addition make the solution more acidic, make it less acidic, or not change the acidity of the original solution? Be sure to fully justify your answer. i You prepare a 1.0-L solution of HA. You then take a 200-mL sample of this solution and place it into a separate container. Would this 200 mL sample be more acidic, be less acidic, or have the same acidity as the original 1.0-L solution of HA(aq)? Be sure to support your answer.
What is a salt? List some anions that behave as weak bases in water. List some anions that have no basic properties in water. List some cations that behave as weak acids in water. List some cations that have no acidic properties in water. Using these lists, give some formulas for salts that have only weak base properties in water. What strategy would you use to solve for the pH of these basic salt solutions? Identify some salts that have only weak acid properties in water. What strategy would you use to solve for the pH of these acidic salt solutions? Identify some salts that have no acidic or basic properties in water (produce neutral solutions). When a salt contains both a weak acid ion and a weak base ion, how do you predict whether the solution pH is acidic, basic, or neutral?
Two strategies are also followed when solving for the pH of a base in water. What is the strategy for calculating the pH of a strong base in water? List the strong bases mentioned in the text that should be committed to memory. Why is calculating the pH of Ca(OH)2 solutions a little more difficult than calculating the pH of NaOH solutions? Most bases are weak bases. The presence of what element most commonly results in basic properties for an organic compound? What is present on this element in compounds that allows it to accept a proton? Table 13-3 and Appendix 5 of the text list Kb values for some weak bases. What strategy is used to solve for the pH of a weak base in water? What assumptions are made when solving for the pH of weak base solutions? If the 5% rule fails, how do you calculate the pH of a weak base in water?
You are asked to determine whether an unknown white solid is acidic or basic. You also need to say whether the acid or base is weak or strong. You are given the molar mass of the solid and told that it is soluble in water. Describe an experiment that you can perform to obtain the desired characteristics of the white solid.
. The concepts of acid-base equilibria were developed in this chapter for aqueous solutions (in aqueous solutions, water is the solvent and is intimately involved in the equilibria). However, the Brønsted-Lowry acid-base theory can be extended easily to other solvents. One such solvent that has been investigated in depth is liquid ammonia. NH3. a. Write a chemical equation indicating how HCl behaves as an acid in liquid ammonia. b. Write a chemical equation indicating how OH- behaves as a base in liquid ammonia.
To measure the relative strengths of bases stronger than OH, it is necessary to choose a solvent that is a weaker acid than water. One such solvent is liquid ammonia. (a) Write a chemical equation for the autoionization of ammonia. (b) What is the strongest acid and base that can exist in liquid ammonia? (c) Will a solution of HCI in liquid ammonia be a strong electrical conductor, a weak conductor, or a nonconductor? (d) Oxide ion (O2) is a stronger base than the amide ion (NH2). Write an equation for the reaction of O2 with NH3 in liquid ammonia. Will the equilibrium favor products or reactants?
Students are often surprised to learn that organic acids, such as acetic acid, contain OH groups. Actually, all oxyacids contain hydroxyl groups. Sulfuric acid, usually written as H2SO4, has the structural formula SO2(OH)2, where S is the central atom. Identify the acids whose structural formulas are shown below. Why do they behave as acids, while NaOH and KOH are bases? a. SO(OH)2 b. ClO2(OH) c. HPO(OH)2
A base is a substance that dissociates in water into one or more ______ ions and one or more ________. a.hydrogen . . . anions b.hydrogen . . . cations c.hydroxide . . . anions d.hydroxide . . . cations
Consider a solution prepared by mixing a weak acid HA. HCl, and NaA. Which of the following statements best describes what happens? a. The H+ from the HCl reacts completely with the A from the NaA. Then the HA dissociates somewhat. b. The H+ from the HCl reacts somewhat with the A from the NaA to make HA, while the HA is dissociating. Eventually you have equal amounts of everything. c. The H+ from the HCl reacts somewhat with the A from the NaA to make HA while the HA is dissociating. Eventually all the reactions have equal rates. d. The H+ from the HCl reacts completely with the A from the NaA. Then the HA dissociates somewhat until too much H+ and A are formed, so the H+ and A react to form HA, and so on. Eventually equilibrium is reached. Justify your choice, and for choices you did not pick, explain what is wrong with them.
Aqueous Solutions of Acids, Bases, and Salts a For each of the following salts, write the reaction that occurs when it dissociates in water: NaCl(s), NaCN(s), KClO2(s), NH4NO3(s), KBr(aq), and NaF(s). b Consider each of the reactions that you wrote above, and identify the aqueous ions that could be proton donors (acids) or proton acceptors (bases). Briefly explain how you decided which ions to choose. c For each of the acids and bases that you identified in pan b, write the chemical reaction it can undergo in aqueous solution (its reaction with water). d Are there any reactions that you have written above that you anticipate will occur to such an extent that the pH of the solution will be affected? As pan of your answer, be sure to explain how you decided. e Assume that in each case above, 0.01 mol of the salt was dissolved in enough water at 25C to make 1.0 L of solution. In each case what additional information would you need in order to calculate the pH? If there are cases where no additional information is required, be sure to state that as well. f Say you take 0.01 mol of NH4CN and dissolve it in enough water at 25C to make 1.0 L of solution. Using chemical reactions and words, explain how you would go about determining what effect this salt will have on the pH of the solution. Be sure to list any additional information you would need to arrive at an answer.
A certain sodium compound is dissolved in water to liberate Na+ ions and a certain negative ion. What evidence would you look for to determine whether the anion is behaving as an acid or a base? How could you tell whether the anion is a strong base? Explain how the anion could behave simultaneously as an acid and a base