For the reaction 2 NO(g) + Cl2(g) → 2 NOCl(g), there are two proposed mechanisms: (I) 2 NO → N2O2 (fast) N2O2 + Cl2 → 2 NOCl (slow) (II) NO+ Cl2 → NOCl2 (fast) NOCl2+ NO → 2 NOCl (slow) The overall reaction is second-order in NO and first-order in Cl2. Which mechanism(s) rationalize the experimental rate law? mechnaism 1 onl 2 mechanism 2 only both mechanism 1 and 2 neither
For the reaction 2 NO(g) + Cl2(g) → 2 NOCl(g), there are two proposed mechanisms: (I) 2 NO → N2O2 (fast) N2O2 + Cl2 → 2 NOCl (slow) (II) NO+ Cl2 → NOCl2 (fast) NOCl2+ NO → 2 NOCl (slow) The overall reaction is second-order in NO and first-order in Cl2. Which mechanism(s) rationalize the experimental rate law? mechnaism 1 onl 2 mechanism 2 only both mechanism 1 and 2 neither
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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For the reaction 2 NO(g) + Cl2(g) → 2 NOCl(g), there are two proposed mechanisms:
(I) 2 NO → N2O2 (fast)
N2O2 + Cl2 → 2 NOCl (slow)
(II) NO+ Cl2 → NOCl2 (fast)
NOCl2+ NO → 2 NOCl (slow)
The overall reaction is second-order in NO and first-order in Cl2. Which mechanism(s) rationalize the experimental rate law?
mechnaism 1 onl 2
mechanism 2 only
both mechanism 1 and 2
neither
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