For Part B: Use the rate law determined above (integer values for the orders of reaction - m, n, and p – and the properly rounded average value for the rate constant, k) to predict (using equation 2) the rate of reaction for the mixture you ran in Part B. Equation 2: rate = k [acetone]" [I;]" [H°P • Then use this rate to calculate (using equation 4) how long (t) you would EXPECT it to take for the Iz color to disappear from this mixture. Equation 4: [12] - 2lo t-to All2] 0 -12]o [12 ]o rate = At t-0 t • Compare this theoretically calculated time to the time you experimentally measured in Part B as % error. %error= (standard/ average)*100%

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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Using the following information from the table and previous completed questions complete part B
[12]o
Mixture
[Acetone],
[H.]o
[L]o
Rate =
avg. time
A1
.8
.2
.001
4.17*10^-6
A2
1.6
.2
.001
8.5*10^-6
АЗ
.8
.4
.001
8.16*10^-6
A4
.8
.2
.0005
4.17*10^-6
В
1.2
.3
.001
8.33*10^-6
Transcribed Image Text:[12]o Mixture [Acetone], [H.]o [L]o Rate = avg. time A1 .8 .2 .001 4.17*10^-6 A2 1.6 .2 .001 8.5*10^-6 АЗ .8 .4 .001 8.16*10^-6 A4 .8 .2 .0005 4.17*10^-6 В 1.2 .3 .001 8.33*10^-6
For Part A: Using the data for mixtures A1-A4, calculate:
• the order of reaction with respect to acetone (i.e., the value of m in equation 2). M=1
• the order of reaction with respect to H* (i.e., the value of p in equation 2) P=0
• the order of reaction with respect to I, (i.e., the value of n in equation 2) N=1
Note: Calculate each order of reaction to ±0.01, and also the value rounded to an integer. Use
the integer value in all subsequent calculations.
• Once you have the rate law calculate the value of the rate constant, k, for each of your four
mixtures (and round each properly). And then calculate the average value for the rate constant.
Include the units for k.
Rate law:
4.17x10^-6 =K [.8]^1[.2]^1[.001]^0
K=2.60*10^-5M^-1s^-1
For Part B:
Use the rate law determined above (integer values for the orders of reaction
the properly rounded average value for the rate constant, k) to predict (using equation 2) the rate
of reaction for the mixture you ran in Part B.
т, п, and p —and
Equation 2: rate = k [acetone]" [I;]" [H°P'
• Then use this rate to calculate (using equation 4) how long (t) you would EXPECT it to take for
the I, color to disappear from this mixture.
Equation 4:
[12] – 12]o
t-to
All2]
[12]o
t
rate =
At
t-0
=
Compare this theoretically calculated time to the time you experimentally measured in Part B as
% error.
%error= (standard/ average)*100%
Transcribed Image Text:For Part A: Using the data for mixtures A1-A4, calculate: • the order of reaction with respect to acetone (i.e., the value of m in equation 2). M=1 • the order of reaction with respect to H* (i.e., the value of p in equation 2) P=0 • the order of reaction with respect to I, (i.e., the value of n in equation 2) N=1 Note: Calculate each order of reaction to ±0.01, and also the value rounded to an integer. Use the integer value in all subsequent calculations. • Once you have the rate law calculate the value of the rate constant, k, for each of your four mixtures (and round each properly). And then calculate the average value for the rate constant. Include the units for k. Rate law: 4.17x10^-6 =K [.8]^1[.2]^1[.001]^0 K=2.60*10^-5M^-1s^-1 For Part B: Use the rate law determined above (integer values for the orders of reaction the properly rounded average value for the rate constant, k) to predict (using equation 2) the rate of reaction for the mixture you ran in Part B. т, п, and p —and Equation 2: rate = k [acetone]" [I;]" [H°P' • Then use this rate to calculate (using equation 4) how long (t) you would EXPECT it to take for the I, color to disappear from this mixture. Equation 4: [12] – 12]o t-to All2] [12]o t rate = At t-0 = Compare this theoretically calculated time to the time you experimentally measured in Part B as % error. %error= (standard/ average)*100%
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