Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:**Question:**
For each pair, select the stronger nucleophile:
- Pair I: H₂O (I) or HO⁻ (II)
- Pair II: Cl⁻ (III) or I⁻ (IV)
**Select one:**
- a. II and IV
- b. II and III
- c. I and III
- d. I and IV
**Explanation:**
The image presents a question about selecting stronger nucleophiles from given pairs. In the first pair, H₂O and HO⁻ are compared. HO⁻ is a stronger nucleophile due to its negative charge, making it more reactive compared to neutral H₂O. In the second pair, Cl⁻ and I⁻ are compared. Generally, in polar protic solvents, I⁻ is a stronger nucleophile than Cl⁻ due to its larger size and ability to more easily donate electrons as a result of less solvation by the solvent.
The correct option is therefore "a. II and IV."
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