For each of these compounds, draw an alkyl halide that can be used to produce it in an Sₙ1 reaction. Then, determine whether the alkyl halide would need to be treated with water or methanol.### Desired Product**(a)** - Structural representation: A six-membered ring with one hydroxyl group (OH) attached.**(b)** - Structural representation: A three-carbon chain with an OCH₃ group (methoxy group) attached to the second carbon.**Table:**- **Starting Alkyl Halide:** Draw the appropriate starting alkyl halide based on the desired product.- **Solvent Used to Treat Alkyl Halide (H₂O or CH₃OH):** Determine whether the alkyl halide needs to be treated with water or methanol to achieve the desired product.

Tertiary alkyl halide reacts with solvent (water or methanol) to give a solvolysis reaction. The solvolysis reaction is followed by the SN1 reaction mechanism.The unimolecular nucleophilic substitution reaction (SN1) proceeds in two steps. In the first step, the leaving group removed from the substrate, and the carbocation intermediate is formed. This step is a slow and rate-determining step. The rate of this step depends on the stability of the carbocation intermediate. The higher the stability of the carbonation intermediates the higher will be the rate of reaction.In the second step, the nucleophile adds to the carbocation intermediate to form the final product.a. The desired alcohol formed as follows: Allylic bromide is a good substrate for the SN1 reaction. The product of the hydrolysis reaction of the allylic bromide is alcohol. The starting alkyl halide is = 3-bromocyclohex-1-ene The solvent used = H2Ob. The desired ether is formed as follows: Tertiary alkyl halide gives SN1 reaction in the methanol solvent to form the ether. The reaction proceeds by the carbonation intermediate. The starting alkyl halide is = 3-bromo-3-methylpentane The solvent used = H2O

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For each of these compounds, draw an alkyl halide that can be used to produce it in an SN1 reaction. Then, determine whether the alkyl halide would need to be treated with water or methanol. Desired Starting alkyl Solvent used to treat alkyl halide (H2O or Product halide CH3OH) (a) OH (b) OCH,

For each of these compounds, draw an alkyl halide that can be used to produce it in an SN1 reaction. Then, determine whether the alkyl halide would need to be treated with water or methanol. Desired Starting alkyl Solvent used to treat alkyl halide (H2O or Product halide CH3OH) (a) OH (b) OCH,

Chemistry for Today: General, Organic, and Biochemistry

9th Edition

ISBN:9781305960060

Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen

Publisher:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen

Chapter14: Aldehydes And Ketones

Section: Chapter Questions

Problem 14.55E: The addition of water to aldehydes and ketones occurs rapidly, although it is not thermodynamically...

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Concept explainers

Aldehydes and Ketones

Aldehydes and ketones are organic compounds that have a carbonyl group, C = O, as their functional group. They both differ in the placement of this carbonyl group in their structures.

Question

For each of these compounds, draw an alkyl halide that can be used to produce it in an Sₙ1 reaction. Then, determine whether the alkyl halide would need to be treated with water or methanol.

### Desired Product

**(a)**
- Structural representation: A six-membered ring with one hydroxyl group (OH) attached.

**(b)**
- Structural representation: A three-carbon chain with an OCH₃ group (methoxy group) attached to the second carbon.

**Table:**

- **Starting Alkyl Halide:** Draw the appropriate starting alkyl halide based on the desired product.
- **Solvent Used to Treat Alkyl Halide (H₂O or CH₃OH):** Determine whether the alkyl halide needs to be treated with water or methanol to achieve the desired product.

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