3 For each of the following bases, determine which type of mechanism would be favored by an elimination reaction using this base. Also, decide the type of majorproducts the elimination reaction would create.BaseDBNIZ:NElimination Mechanism(choose one)E1 mechanismOE2 mechanismE1 mechanismE2 mechanismE1 mechanismOE2 mechanism0Major Elimination Products(choose all that apply)ZaitsevHofmannZaitsevHofmannZaitsevHofmannXŚ

A bulky base prefers the elimination reaction by extracting the proton from the less hindered side of the alkyl chain and undergoing E2- elimination reaction.A less bulky base prefers the abstraction of acidic hydrogen from the more substituted, hence hindered side and undergoes E1- elimination reaction.Both the elimination reactions favor Zaitsev products unless there is a special case like, when the leaving group is charged ammonium ion, Hoffmann product is formed as major product.Base DBU is a very strong base and thus will prefer E2- elimination reaction. The major product will be the Zaitsev product.Tertiary amines are considered a strong base and so will prefer E2- elimination reaction. The major product will be the Zaitsev product.Secondary amines are considered weak bases and so will prefer E1- elimination reaction. The major product will be the Zaitsev product.The major product in general is Zaitsev product. However, the product formation also depends on the leaving group of the reactant.BaseElimination reactionMajor productDBUE2ZaitsevTertiary amineE2ZaitsevSecondary amineE1Zaitsev

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For each of the following bases, determine which type of mechanism would be favored by an elimination reaction using this base. Also, decide the type of major products the elimination reaction would create. Base N DBN N Elimination Mechanism (choose one) OE1 mechanism OE2 mechanism E1 mechanism OE2 mechanism E1 mechanism E2 mechanism Major Elimination Products (choose all that apply) Zaitsev Hofmann Zaitsev Hofmann Zaitsev Hofmann X 5

For each of the following bases, determine which type of mechanism would be favored by an elimination reaction using this base. Also, decide the type of major products the elimination reaction would create. Base N DBN N Elimination Mechanism (choose one) OE1 mechanism OE2 mechanism E1 mechanism OE2 mechanism E1 mechanism E2 mechanism Major Elimination Products (choose all that apply) Zaitsev Hofmann Zaitsev Hofmann Zaitsev Hofmann X 5

Chemistry

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ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

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Designing a Synthesis

Organic synthesis is a branch of chemical synthesis that involves the planned construction of organic compounds/molecules from smaller units that possess functional groups. Friedrich Wöhler was the first scientist who designed the synthesis of an organic compound, urea from inorganic starting materials silver cyanate with ammonium chloride via a simple, one-step synthesis.

Question

For each of the following bases, determine which type of mechanism would be favored by an elimination reaction using this base. Also, decide the type of major
products the elimination reaction would create.
Base
DBN
IZ:
N
Elimination Mechanism
(choose one)
E1 mechanism
OE2 mechanism
E1 mechanism
E2 mechanism
E1 mechanism
OE2 mechanism
0
Major Elimination Products
(choose all that apply)
Zaitsev
Hofmann
Zaitsev
Hofmann
Zaitsev
Hofmann
X
Ś

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