For a system involving complexation, the [Ag+] can be replaced using the formation constant of the reaction, Ag+ + 2 S2O32- ⇌ Ag(S2O3)23-. Show the process of obtaining the formation constant.

Chemistry: Principles and Practice
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Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
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Chapter18: Electrochemistry
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For a system involving complexation, the [Ag+] can be replaced using the formation constant of the reaction, Ag+ + 2 S2O32- ⇌ Ag(S2O3)23-. Show the process of obtaining the formation constant.

 

Each electrode reaction is the sum of two reactions,
Precipitation: AgCI(s) = Ag*+ CF
plus Ag*+ e = Ag(s)
Complexation: Ag* + 2 S2032 = Ag(S2O3)23 plus Ag*+ e = Ag(s)
Transcribed Image Text:Each electrode reaction is the sum of two reactions, Precipitation: AgCI(s) = Ag*+ CF plus Ag*+ e = Ag(s) Complexation: Ag* + 2 S2032 = Ag(S2O3)23 plus Ag*+ e = Ag(s)
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