For 1,2-dibromoethane, the energy of "anti" conformation (1) is 1.0 kJ/mol lower than the energy of "gauche" conformations (2 and 3). Assuming that number of molecules in the eclipsed conformations (shown on top) is negligible, what % of 1,2-dibromoethane will be in "gauche" conformation at 300K.
For 1,2-dibromoethane, the energy of "anti" conformation (1) is 1.0 kJ/mol lower than the energy of "gauche" conformations (2 and 3). Assuming that number of molecules in the eclipsed conformations (shown on top) is negligible, what % of 1,2-dibromoethane will be in "gauche" conformation at 300K.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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For 1,2-dibromoethane, the energy of "anti" conformation (1) is 1.0 kJ/mol lower than the energy of "gauche" conformations (2 and 3). Assuming that number of molecules in the eclipsed conformations (shown on top) is negligible, what % of 1,2-dibromoethane will be in "gauche" conformation at 300K.

Transcribed Image Text:←6100²
BH
Br
'H
H.
H
Br
H
unequal
energy levels
H₁
Br
H
Br conf: 1
I I
unequal
barrier
heights
H
Br
H
Br
BBr
H
H cont: 2
H
Br
H
Br
卧
H
H
H conf: 3
Br
H
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